Mild and general cross-coupling of (α-alkoxyvinyl)silanols and -silyl hydrides

Scott E. Denmark, Luc Neuville

Research output: Contribution to journalArticlepeer-review

Abstract

(Matrix presented) (α-Alkoxyvinyl)silanols and (α-alkoxyvinyl)silyl hydrides are efficiently converted to aryl vinyl ethers by a palladium(0)-catalyzed cross-coupling reaction with aryl halides in the presence of tetrabutylammonium fluoride or hydroxide. Yields are generally high, and the reaction is compatible with a wide range of functional groups.

Original languageEnglish (US)
Pages (from-to)3221-3224
Number of pages4
JournalOrganic Letters
Volume2
Issue number20
DOIs
StatePublished - Oct 5 2000

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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