Microscopic theory of rubber elasticity

Folusho T. Oyerokun, Kenneth S. Schweizer

Research output: Contribution to journalArticlepeer-review

Abstract

A microscopic theory of rubber elasticity in polymer liquids and networks was developed. The theory predicts strain induced softening, and a nonclassical intermolecular contribution to the linear modulus. Quantitative comparison of the theory with experiments on polydimethylsiloxane networks were also performed. The theory is generalizable to treat the structure, thermodynamics and mechanical response of nematic elastomers.

Original languageEnglish (US)
Pages (from-to)9359-9370
Number of pages12
JournalJournal of Chemical Physics
Volume120
Issue number19
DOIs
StatePublished - May 15 2004

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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