Abstract
We report on a pH sensor with ultrahigh sensitivity based on a microcantilever structure with a lithographically-defined crosslinked copolymeric hydrogel. Silicon-on-insulator wafers were used to fabricate cantilevers on which a polymer consisting of poly(methacrylic acid) (PMAA) with poly(ethylene glycol) dimethacrylate was patterned using free-radical UV polymerization. As the pH around the cantilever was increased above the pK a of PMAA, the polymer network expanded and resulted in a reversible change in surface stress causing the microcantilever to bend. Excellent mechanical amplification of polymer swelling as a function of pH change within the dynamic range was obtained, with a maximum deflection sensitivity of 1nm/5×10-5ΔpH.
Original language | English (US) |
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Pages (from-to) | 3091-3093 |
Number of pages | 3 |
Journal | Applied Physics Letters |
Volume | 81 |
Issue number | 16 |
DOIs | |
State | Published - Oct 14 2002 |
Externally published | Yes |
ASJC Scopus subject areas
- Physics and Astronomy (miscellaneous)