Microfiltration of polyoxyalkylene metalworking fluid lubricant additives using aluminum oxide membranes

Steven J. Skerlos, N. Rajagopalan, Richard E. DeVor, Shiv G. Kapoor, V. Don Angspatt

Research output: Contribution to journalArticle

Abstract

Microfiltration is capable of reducing health hazards and environmental pollution associated with metalworking fluids (MWFs) by enabling recycling and microbial removal. This paper investigates chemical characteristics of MWFs that can lead to flux decline during microfiltration using aluminum oxide membranes by studying the family of polyoxyalkylene diblock copolymers comprised of ethylene oxide and propylene oxide. These copolymers are commonly used as lubricant additives in metalworking fluids and serve as a model for beginning to understand the relationship between metalworking fluid formulation and microfiltration flux. It is found that increasing the hydrophobic content of the copolymers can lead to reduced flux. Anionic modification and increasing molecular weight of the copolymers can also lead to reduced flux. Insufficient cleaning of anionic copolymers from the membrane leads to pH-dependent flux of deionized water during subsequent filtration. The pH-dependence of flux arises due to swelling caused by electrostatic repulsions between the aluminum oxide surface and anionic copolymers that remain adsorbed to the surface of the membrane. This swelling serves to resist permeate flow above the isoelectric point of aluminum oxide. This phenomenon is observed directly using Field Emission Environmental Scanning Electron Microscopy (FE-ESEM).

Original languageEnglish (US)
Pages (from-to)692-699
Number of pages8
JournalJournal of Manufacturing Science and Engineering, Transactions of the ASME
Volume123
Issue number4
StatePublished - Nov 2001

Fingerprint

Fluxes
Oxides
Copolymers
Fluids
Microfiltration
Membranes
Aluminum
Swelling
Lubricants
Health hazards
Deionized water
Field emission
Block copolymers
Propylene
Recycling
Electrostatics
Cleaning
Ethylene
Pollution
Molecular weight

ASJC Scopus subject areas

  • Industrial and Manufacturing Engineering
  • Mechanical Engineering

Cite this

Microfiltration of polyoxyalkylene metalworking fluid lubricant additives using aluminum oxide membranes. / Skerlos, Steven J.; Rajagopalan, N.; DeVor, Richard E.; Kapoor, Shiv G.; Angspatt, V. Don.

In: Journal of Manufacturing Science and Engineering, Transactions of the ASME, Vol. 123, No. 4, 11.2001, p. 692-699.

Research output: Contribution to journalArticle

Skerlos, Steven J.; Rajagopalan, N.; DeVor, Richard E.; Kapoor, Shiv G.; Angspatt, V. Don / Microfiltration of polyoxyalkylene metalworking fluid lubricant additives using aluminum oxide membranes.

In: Journal of Manufacturing Science and Engineering, Transactions of the ASME, Vol. 123, No. 4, 11.2001, p. 692-699.

Research output: Contribution to journalArticle

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