Metal-induced gap states at a carbon-nanotube intramolecular heterojunction observed by scanning tunneling microscopy

Laura B. Ruppalt, Joseph W. Lyding

Research output: Contribution to journalArticlepeer-review

Abstract

The electronic transition at a metal-semiconductor (M-S) heterojunction within a single-walled carbon nanotubes (SWNT) at the sub-nanometer scale, is characterized through ultrahigh vacuum scanning tunneling microscopy (UHV-STM). STM images show a well-defined physical transition region between semiconducting and metallic nanotube segments while tunneling spectra indicate a gradual transition in SWNT conducting behavior. STM studies of SWNT/III-V systems indicates that charge transfer from the n-InAs(110) surface generally induce p-type behavior within supported semiconducting SWNTs. Scanning tunneling spectroscopy (STS) measurement confirmed the existence of metal-induced gap states (MIGS)originating at the junction interface, with enhanced conductance nanotube segment. Energetically-resolved current image tunneling spectroscopy (CITS) data enabled a quantitative evaluation of the evanscent-state decay.

Original languageEnglish (US)
Pages (from-to)280-284
Number of pages5
JournalSmall
Volume3
Issue number2
DOIs
StatePublished - Feb 2007

Keywords

  • Carbon nanotubes
  • Heterojunctions
  • Molecular electronics
  • Scanning tunneling microscopy
  • Semiconductors

ASJC Scopus subject areas

  • General Chemistry
  • Engineering (miscellaneous)
  • Biotechnology
  • General Materials Science
  • Biomaterials

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