Mechanistic studies on the thiation of carbonyls by Lawesson's reagent: The role of a 3-coordinate phosphorus(V) species.

Thomas Rauchfuss; Gregg A. Zank

doi:10.1016/S0040-4039(00)84818-2

Mechanistic studies on the thiation of carbonyls by Lawesson's reagent

The role of a 3-coordinate phosphorus(V) species.

Thomas Rauchfuss, Gregg A. Zank

Chemistry

Research output: Contribution to journal › Article

Abstract

Structural, kinetic, and spectroscopic studies show that the mechanism for the thiation of organic carbonyls by Lawesson's reagent involves momomeric RPS₂ intermediates.

Original language	English (US)
Pages (from-to)	3445-3448
Number of pages	4
Journal	Tetrahedron Letters
Volume	27
Issue number	30
DOIs	https://doi.org/10.1016/S0040-4039(00)84818-2
State	Published - Jan 1 1986

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2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide

Phosphorus

Kinetics

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Cite this

Rauchfuss, T., & Zank, G. A. (1986). Mechanistic studies on the thiation of carbonyls by Lawesson's reagent: The role of a 3-coordinate phosphorus(V) species. Tetrahedron Letters, 27(30), 3445-3448. https://doi.org/10.1016/S0040-4039(00)84818-2

Mechanistic studies on the thiation of carbonyls by Lawesson's reagent : The role of a 3-coordinate phosphorus(V) species. / Rauchfuss, Thomas; Zank, Gregg A.

In: Tetrahedron Letters, Vol. 27, No. 30, 01.01.1986, p. 3445-3448.

Research output: Contribution to journal › Article

Rauchfuss, T & Zank, GA 1986, 'Mechanistic studies on the thiation of carbonyls by Lawesson's reagent: The role of a 3-coordinate phosphorus(V) species.', Tetrahedron Letters, vol. 27, no. 30, pp. 3445-3448. https://doi.org/10.1016/S0040-4039(00)84818-2

Rauchfuss T, Zank GA. Mechanistic studies on the thiation of carbonyls by Lawesson's reagent: The role of a 3-coordinate phosphorus(V) species. Tetrahedron Letters. 1986 Jan 1;27(30):3445-3448. https://doi.org/10.1016/S0040-4039(00)84818-2

Rauchfuss, Thomas ; Zank, Gregg A. / Mechanistic studies on the thiation of carbonyls by Lawesson's reagent : The role of a 3-coordinate phosphorus(V) species. In: Tetrahedron Letters. 1986 ; Vol. 27, No. 30. pp. 3445-3448.

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10.1016/S0040-4039(00)84818-2