Mechanistic studies on the thiation of carbonyls by Lawesson's reagent: The role of a 3-coordinate phosphorus(V) species.

Thomas Rauchfuss, Gregg A. Zank

Research output: Contribution to journalArticle

Abstract

Structural, kinetic, and spectroscopic studies show that the mechanism for the thiation of organic carbonyls by Lawesson's reagent involves momomeric RPS2 intermediates.

Original languageEnglish (US)
Pages (from-to)3445-3448
Number of pages4
JournalTetrahedron Letters
Volume27
Issue number30
DOIs
StatePublished - 1986

Fingerprint

2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disulfide
Phosphorus
Kinetics

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Mechanistic studies on the thiation of carbonyls by Lawesson's reagent : The role of a 3-coordinate phosphorus(V) species. / Rauchfuss, Thomas; Zank, Gregg A.

In: Tetrahedron Letters, Vol. 27, No. 30, 1986, p. 3445-3448.

Research output: Contribution to journalArticle

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