Measurement of radiation-enhanced diffusion of la in single crystal thin film CeO2

Harrison K. Pappas, Brent J. Heuser, Melissa M. Strehle

Research output: Contribution to journalArticlepeer-review

Abstract

The diffusion of La, a trivalent cation dopant, actinide surrogate, and high-yield fission product, in CeO2, a UO2 nuclear fuel surrogate, during 1.8 MeV Kr+ ion bombardment over a temperature range from 673 K to 1206 K has been measured with secondary ion mass spectroscopy. The diffusivity under these irradiation conditions has been analyzed with a model based on a combination of sink-limited and recombination-limited kinetics. This analysis yielded a cation vacancy migration energy of Emv ∼ 0.4 eV below ∼800 K, were recombination-limited kinetics dominated the behavior. The thermal diffusivity of La in the same system was measured over a range of 873-1073 K and was characterized by an activation enthalpy of Ea=Efv+Emv∼1.4eV. The measurement of both the migration enthalpy and total activation enthalpy separately allows the vacancy formation enthalpy on the cation sublattice to be determined; Efv ∼ 1 eV. The mixing parameter under energetic heavy-ion bombardment at room temperature was measured as well and found to be ∼4 × 10-5 nm 5/eV.

Original languageEnglish (US)
Pages (from-to)118-125
Number of pages8
JournalJournal of Nuclear Materials
Volume405
Issue number2
DOIs
StatePublished - Oct 15 2010

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Materials Science(all)
  • Nuclear Energy and Engineering

Fingerprint Dive into the research topics of 'Measurement of radiation-enhanced diffusion of la in single crystal thin film CeO<sub>2</sub>'. Together they form a unique fingerprint.

Cite this