[Me 8Pt 4ReS 4] - and related PtMe 2-containing clusters derived from tetrathiorhenate

Haijun Yao; Thomas B. Rauchfuss; Scott R. Wilson

doi:10.1016/j.jorganchem.2004.09.010

[Me ₈Pt ₄ReS ₄] ^- and related PtMe ₂-containing clusters derived from tetrathiorhenate

Haijun Yao, Thomas B. Rauchfuss, Scott R. Wilson

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The reactions of Pt ₂Me ₄(μ-SMe ₂) ₂ and [ReS ₄] ^- in MeCN solution have been investigated. The resulting polyalkylated clusters: Et ₄N[ReS ₄PtMe ₂] (Et ₄N[1]), Et ₄N[ReS ₄(PtMe ₂) ₂] (Et ₄N[2]), and Et ₄N[ReS ₄(PtMe ₂) ₄] (Et ₄N[4]), were characterized by ¹H, ¹³C, ¹⁹⁵Pt NMR spectroscopy and ESI mass spectrometry. The structure of Et ₄N[1] was confirmed by single crystal X-ray diffraction, which demonstrated the expected square planar and tetrahedral coordination spheres bridged by a pair of sulfur atoms.

Original language	English (US)
Pages (from-to)	193-196
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	690
Issue number	1
DOIs	https://doi.org/10.1016/j.jorganchem.2004.09.010
State	Published - Jan 3 2005

Keywords

Cluster
Platinum
Rhenium
Sulfide

ASJC Scopus subject areas

Chemical Engineering (miscellaneous)
Materials Science (miscellaneous)
Materials Chemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Biochemistry

Online availability

10.1016/j.jorganchem.2004.09.010

Library availability

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Cite this

@article{b69af45d4f104d3988c66d52007cb747,

title = "[Me 8Pt 4ReS 4] - and related PtMe 2-containing clusters derived from tetrathiorhenate",

abstract = "The reactions of Pt 2Me 4(μ-SMe 2) 2 and [ReS 4] - in MeCN solution have been investigated. The resulting polyalkylated clusters: Et 4N[ReS 4PtMe 2] (Et 4N[1]), Et 4N[ReS 4(PtMe 2) 2] (Et 4N[2]), and Et 4N[ReS 4(PtMe 2) 4] (Et 4N[4]), were characterized by 1H, 13C, 195Pt NMR spectroscopy and ESI mass spectrometry. The structure of Et 4N[1] was confirmed by single crystal X-ray diffraction, which demonstrated the expected square planar and tetrahedral coordination spheres bridged by a pair of sulfur atoms.",

keywords = "Cluster, Platinum, Rhenium, Sulfide",

author = "Haijun Yao and Rauchfuss, {Thomas B.} and Wilson, {Scott R.}",

year = "2005",

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doi = "10.1016/j.jorganchem.2004.09.010",

language = "English (US)",

volume = "690",

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journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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T1 - [Me 8Pt 4ReS 4] - and related PtMe 2-containing clusters derived from tetrathiorhenate

AU - Yao, Haijun

AU - Rauchfuss, Thomas B.

AU - Wilson, Scott R.

PY - 2005/1/3

Y1 - 2005/1/3

N2 - The reactions of Pt 2Me 4(μ-SMe 2) 2 and [ReS 4] - in MeCN solution have been investigated. The resulting polyalkylated clusters: Et 4N[ReS 4PtMe 2] (Et 4N[1]), Et 4N[ReS 4(PtMe 2) 2] (Et 4N[2]), and Et 4N[ReS 4(PtMe 2) 4] (Et 4N[4]), were characterized by 1H, 13C, 195Pt NMR spectroscopy and ESI mass spectrometry. The structure of Et 4N[1] was confirmed by single crystal X-ray diffraction, which demonstrated the expected square planar and tetrahedral coordination spheres bridged by a pair of sulfur atoms.

AB - The reactions of Pt 2Me 4(μ-SMe 2) 2 and [ReS 4] - in MeCN solution have been investigated. The resulting polyalkylated clusters: Et 4N[ReS 4PtMe 2] (Et 4N[1]), Et 4N[ReS 4(PtMe 2) 2] (Et 4N[2]), and Et 4N[ReS 4(PtMe 2) 4] (Et 4N[4]), were characterized by 1H, 13C, 195Pt NMR spectroscopy and ESI mass spectrometry. The structure of Et 4N[1] was confirmed by single crystal X-ray diffraction, which demonstrated the expected square planar and tetrahedral coordination spheres bridged by a pair of sulfur atoms.

KW - Cluster

KW - Platinum

KW - Rhenium

KW - Sulfide

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