[Me 8Pt 4ReS 4] - and related PtMe 2-containing clusters derived from tetrathiorhenate

Haijun Yao, Thomas B. Rauchfuss, Scott R. Wilson

Research output: Contribution to journalArticle

Abstract

The reactions of Pt 2Me 4(μ-SMe 2) 2 and [ReS 4] - in MeCN solution have been investigated. The resulting polyalkylated clusters: Et 4N[ReS 4PtMe 2] (Et 4N[1]), Et 4N[ReS 4(PtMe 2) 2] (Et 4N[2]), and Et 4N[ReS 4(PtMe 2) 4] (Et 4N[4]), were characterized by 1H, 13C, 195Pt NMR spectroscopy and ESI mass spectrometry. The structure of Et 4N[1] was confirmed by single crystal X-ray diffraction, which demonstrated the expected square planar and tetrahedral coordination spheres bridged by a pair of sulfur atoms.

Original languageEnglish (US)
Pages (from-to)193-196
Number of pages4
JournalJournal of Organometallic Chemistry
Volume690
Issue number1
DOIs
StatePublished - Jan 3 2005

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Keywords

  • Cluster
  • Platinum
  • Rhenium
  • Sulfide

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Materials Science (miscellaneous)
  • Materials Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Biochemistry

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