Abstract
The reactions of Pt 2Me 4(μ-SMe 2) 2 and [ReS 4] - in MeCN solution have been investigated. The resulting polyalkylated clusters: Et 4N[ReS 4PtMe 2] (Et 4N[1]), Et 4N[ReS 4(PtMe 2) 2] (Et 4N[2]), and Et 4N[ReS 4(PtMe 2) 4] (Et 4N[4]), were characterized by 1H, 13C, 195Pt NMR spectroscopy and ESI mass spectrometry. The structure of Et 4N[1] was confirmed by single crystal X-ray diffraction, which demonstrated the expected square planar and tetrahedral coordination spheres bridged by a pair of sulfur atoms.
Original language | English (US) |
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Pages (from-to) | 193-196 |
Number of pages | 4 |
Journal | Journal of Organometallic Chemistry |
Volume | 690 |
Issue number | 1 |
DOIs | |
State | Published - Jan 3 2005 |
Keywords
- Cluster
- Platinum
- Rhenium
- Sulfide
ASJC Scopus subject areas
- Chemical Engineering (miscellaneous)
- Materials Science (miscellaneous)
- Materials Chemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Biochemistry