Magic-angle sample-spinning n.m.r. spectroscopy of an antiferromagnetically coupled copper formate dimer

Thomas H. Walter; Eric Oldfield

doi:10.1039/C39870000646

Magic-angle sample-spinning n.m.r. spectroscopy of an antiferromagnetically coupled copper formate dimer

Thomas H. Walter
, Eric Oldfield

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The first solid-state carbon-13 magic-angle sample-spinning n.m.r. spectra of an antiferromagnetically-coupled species, [Cu(HCO₂) ₂(C₅H₅N)]₂ are reported, the results indicating that essentially diamagnetic behaviour can be observed at -180°C, while increasing temperature results in a shifted and progressively broadened resonance, owing to spin unpairing.

Original language	English (US)
Pages (from-to)	646-647
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39870000646
State	Published - 1987

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Molecular Medicine

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title = "Magic-angle sample-spinning n.m.r. spectroscopy of an antiferromagnetically coupled copper formate dimer",

abstract = "The first solid-state carbon-13 magic-angle sample-spinning n.m.r. spectra of an antiferromagnetically-coupled species, [Cu(HCO2) 2(C5H5N)]2 are reported, the results indicating that essentially diamagnetic behaviour can be observed at -180°C, while increasing temperature results in a shifted and progressively broadened resonance, owing to spin unpairing.",

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AU - Walter, Thomas H.

AU - Oldfield, Eric

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N2 - The first solid-state carbon-13 magic-angle sample-spinning n.m.r. spectra of an antiferromagnetically-coupled species, [Cu(HCO2) 2(C5H5N)]2 are reported, the results indicating that essentially diamagnetic behaviour can be observed at -180°C, while increasing temperature results in a shifted and progressively broadened resonance, owing to spin unpairing.

AB - The first solid-state carbon-13 magic-angle sample-spinning n.m.r. spectra of an antiferromagnetically-coupled species, [Cu(HCO2) 2(C5H5N)]2 are reported, the results indicating that essentially diamagnetic behaviour can be observed at -180°C, while increasing temperature results in a shifted and progressively broadened resonance, owing to spin unpairing.

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JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

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Magic-angle sample-spinning n.m.r. spectroscopy of an antiferromagnetically coupled copper formate dimer

Abstract

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