TY - JOUR
T1 - Magic-angle sample-spinning n.m.r. spectroscopy of an antiferromagnetically coupled copper formate dimer
AU - Walter, Thomas H.
AU - Oldfield, Eric
PY - 1987
Y1 - 1987
N2 - The first solid-state carbon-13 magic-angle sample-spinning n.m.r. spectra of an antiferromagnetically-coupled species, [Cu(HCO2) 2(C5H5N)]2 are reported, the results indicating that essentially diamagnetic behaviour can be observed at -180°C, while increasing temperature results in a shifted and progressively broadened resonance, owing to spin unpairing.
AB - The first solid-state carbon-13 magic-angle sample-spinning n.m.r. spectra of an antiferromagnetically-coupled species, [Cu(HCO2) 2(C5H5N)]2 are reported, the results indicating that essentially diamagnetic behaviour can be observed at -180°C, while increasing temperature results in a shifted and progressively broadened resonance, owing to spin unpairing.
UR - http://www.scopus.com/inward/record.url?scp=37049084771&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049084771&partnerID=8YFLogxK
U2 - 10.1039/C39870000646
DO - 10.1039/C39870000646
M3 - Article
AN - SCOPUS:37049084771
SN - 0022-4936
SP - 646
EP - 647
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 9
ER -