The first solid-state carbon-13 magic-angle sample-spinning n.m.r. spectra of an antiferromagnetically-coupled species, [Cu(HCO2) 2(C5H5N)]2 are reported, the results indicating that essentially diamagnetic behaviour can be observed at -180°C, while increasing temperature results in a shifted and progressively broadened resonance, owing to spin unpairing.
|Original language||English (US)|
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - 1987|
ASJC Scopus subject areas
- Molecular Medicine