Magic-angle sample-spinning n.m.r. spectroscopy of an antiferromagnetically coupled copper formate dimer

Thomas H. Walter, Eric Oldfield

Research output: Contribution to journalArticlepeer-review

Abstract

The first solid-state carbon-13 magic-angle sample-spinning n.m.r. spectra of an antiferromagnetically-coupled species, [Cu(HCO2) 2(C5H5N)]2 are reported, the results indicating that essentially diamagnetic behaviour can be observed at -180°C, while increasing temperature results in a shifted and progressively broadened resonance, owing to spin unpairing.

Original languageEnglish (US)
Pages (from-to)646-647
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number9
DOIs
StatePublished - Dec 1 1987

ASJC Scopus subject areas

  • Molecular Medicine

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