Mössbauer study of Mg, Zn substituted Cr-spinel

M. D. Osborne; M. E. Fleet; G. M. Bancroft

doi:10.1016/0038-1098(83)90046-7

Mössbauer study of Mg, Zn substituted Cr-spinel

M. D. Osborne, M. E. Fleet, G. M. Bancroft

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Abstract

Mössbauer spectra of the oxide spinels Fe_1-xZn_xCr₂O₄ and Fe_1-xMg_xCr₂O₄, with x=0.0 to 0.5, exhibit a singlet only. This suggests that, in complex spinel solid-solutions, substitution of cations into the second coordination sphere does not contribute to anisotropy of the electric field gradient at the nucleus of tetrahedral ferrous iron.

Original language	English (US)
Pages (from-to)	663-664
Number of pages	2
Journal	Solid State Communications
Volume	48
Issue number	8
DOIs	https://doi.org/10.1016/0038-1098(83)90046-7
State	Published - Nov 1983

ASJC Scopus subject areas

Chemistry(all)
Condensed Matter Physics
Materials Chemistry

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title = "M{\"o}ssbauer study of Mg, Zn substituted Cr-spinel",

abstract = "M{\"o}ssbauer spectra of the oxide spinels Fe1-xZnxCr2O4 and Fe1-xMgxCr2O4, with x=0.0 to 0.5, exhibit a singlet only. This suggests that, in complex spinel solid-solutions, substitution of cations into the second coordination sphere does not contribute to anisotropy of the electric field gradient at the nucleus of tetrahedral ferrous iron.",

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year = "1983",

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AU - Osborne, M. D.

AU - Fleet, M. E.

AU - Bancroft, G. M.

PY - 1983/11

Y1 - 1983/11

N2 - Mössbauer spectra of the oxide spinels Fe1-xZnxCr2O4 and Fe1-xMgxCr2O4, with x=0.0 to 0.5, exhibit a singlet only. This suggests that, in complex spinel solid-solutions, substitution of cations into the second coordination sphere does not contribute to anisotropy of the electric field gradient at the nucleus of tetrahedral ferrous iron.

AB - Mössbauer spectra of the oxide spinels Fe1-xZnxCr2O4 and Fe1-xMgxCr2O4, with x=0.0 to 0.5, exhibit a singlet only. This suggests that, in complex spinel solid-solutions, substitution of cations into the second coordination sphere does not contribute to anisotropy of the electric field gradient at the nucleus of tetrahedral ferrous iron.

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Mössbauer study of Mg, Zn substituted Cr-spinel

Abstract

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