Local chain dynamics of adsorbed polystyrene studied by time-resolved fluorescence anisotropy [1]

S. Jeon, Chul Bae Sung Chul Bae, S. Granick

Research output: Contribution to journalLetterpeer-review

Abstract

A study of the exchange dynamics of adsorbed polystyrene polymers considering their dynamic and equilibrium aspects was done. It comprised of direct measurements of the rotational chain segment located within the loops along adsorbed flexible polymer chains. The adsorbed polystyrene showed a second order, anisotropic decay with life time decreasing upon adsorption. The double-exponential function was found sufficient to represent the anisotropy, surface and bulk fluorescence decays.

Original languageEnglish (US)
Pages (from-to)8401-8404
Number of pages4
JournalMacromolecules
Volume34
Issue number24
DOIs
StatePublished - Nov 20 2001

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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