Ligand-mediated addition of organometallic reagents to azomethine functions

Scott E. Denmark; Olivier J.C. Nicaise

doi:10.1039/cc9960000999

Ligand-mediated addition of organometallic reagents to azomethine functions

Scott E. Denmark, Olivier J.C. Nicaise

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Despite the enormous progress made in the asymmetric addition of nucleophiles to prochiral carbonyl compounds for the preparation of chiral alcohols, the corresponding study of enantioselective conversion of prochiral azomethine functions to chiral amines remains a relatively undeveloped area of research. This account reviews the current state of this new field of investigation.

Original language	English (US)
Pages (from-to)	999-1004
Number of pages	6
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/cc9960000999
State	Published - Jan 1 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/cc9960000999

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title = "Ligand-mediated addition of organometallic reagents to azomethine functions",

abstract = "Despite the enormous progress made in the asymmetric addition of nucleophiles to prochiral carbonyl compounds for the preparation of chiral alcohols, the corresponding study of enantioselective conversion of prochiral azomethine functions to chiral amines remains a relatively undeveloped area of research. This account reviews the current state of this new field of investigation.",

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N2 - Despite the enormous progress made in the asymmetric addition of nucleophiles to prochiral carbonyl compounds for the preparation of chiral alcohols, the corresponding study of enantioselective conversion of prochiral azomethine functions to chiral amines remains a relatively undeveloped area of research. This account reviews the current state of this new field of investigation.

AB - Despite the enormous progress made in the asymmetric addition of nucleophiles to prochiral carbonyl compounds for the preparation of chiral alcohols, the corresponding study of enantioselective conversion of prochiral azomethine functions to chiral amines remains a relatively undeveloped area of research. This account reviews the current state of this new field of investigation.

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Ligand-mediated addition of organometallic reagents to azomethine functions

Abstract

ASJC Scopus subject areas

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