TY - JOUR
T1 - Length dependence of the magnetic field modulated triplet yield of photogenerated biradicals
AU - Bittl, R.
AU - Schulten, K.
N1 - Funding Information:
The authors would like to thank R. Treichel, H. Staerk and A. Weller for generously sharing and discussing their experimental results. This work has been supported by Deutsche Forschungsgemeinschaft (SFB 143-CI) as well as by the National Center for Supercomputer Applications at the University of Illinois.
PY - 1988/4/29
Y1 - 1988/4/29
N2 - The magnetic field dependence of the triplet yield of biradicals of the type 2A+-(CH2)n-2D- has been calculated for three different lengths n = 8, 9, and 10 of the linking aliphatic chain. The calculations are based on the solution of the stochastic Liouville equation under the assumption of a "through space" exchange interaction and compare well with experimental observations. We show that the field dependence of the triplet yield is governed by the "spectrum of the exchange interaction".
AB - The magnetic field dependence of the triplet yield of biradicals of the type 2A+-(CH2)n-2D- has been calculated for three different lengths n = 8, 9, and 10 of the linking aliphatic chain. The calculations are based on the solution of the stochastic Liouville equation under the assumption of a "through space" exchange interaction and compare well with experimental observations. We show that the field dependence of the triplet yield is governed by the "spectrum of the exchange interaction".
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U2 - 10.1016/0009-2614(88)85048-6
DO - 10.1016/0009-2614(88)85048-6
M3 - Article
AN - SCOPUS:0040249945
SN - 0009-2614
VL - 146
SP - 58
EP - 62
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-2
ER -