Kr and Xe irradiations in lanthanum (La) doped ceria: Study at the high dose regime

Di Yun, Aaron J. Oaks, Wei Ying Chen, Marquis A. Kirk, Jeffrey Rest, Zinetula Z. Insopov, Abdellatif M. Yacout, James F. Stubbins

Research output: Contribution to journalArticle

Abstract

In order to understand cavity and bubble formation and growth in oxide nuclear fuel materials, ion beam irradiation experiments were conducted with two common fission gas species: Kr and Xe. Ceria (CeO2) was selected as a surrogate material for uranium dioxide (UO2) due to its many similar properties to UO2. Ion beam energies were chosen such that both cavities and gas bubbles structures were induced by ion irradiations. The ion irradiation experiments were carried out at 600 °C, at which temperature, cavity/gas bubble structures are believed to be immobile in this material. Lanthanum (La) was chosen as a dopant in CeO2 to investigate the effect of impurities. The presence of La in the CeO2 lattice also introduces a predictable initial concentration of oxygen vacancies, similar to the introduction of oxygen vacancies by the existence of Pu 3+ in MOX fuel [1]. The influence of two La concentrations, 5% and 25%, were examined. The study focused on the high dose regime where cavity/gas bubble structures were clearly identifiable with their sizes and number densities readily measurable. Cavity/gas bubble coarsening by coalescence was identified with TEM (Transmission Electron Microscopy) characterizations of as-irradiated La doped CeO2 specimens. The results revealed that lanthanum trapping has significant influence on the cavity/bubble growth in the material lattice by comparing the cavity/gas bubble size distributions between 5% La doped ceria and 25% La doped ceria. Lattice and kinetic Monte Carlo calculations described in a previous work have provided insights to the interpretations of the experimental results [2]. Solid state Xe precipitates were observed in low energy Xe implantation in 5% La doped ceria to a very high fluence of 1 × 1017 ions/cm2 at 600 °C. The solid state Xe precipitate structures are represented by faceted morphology. Very similar observations of solid state/near solid state Xe bubbles were made by Nogita et al. in the outer region of UO2 pellet irradiated to a pellet average burnup of 49 GWd/t [3].

Original languageEnglish (US)
Pages (from-to)80-86
Number of pages7
JournalJournal of Nuclear Materials
Volume418
Issue number1-3
DOIs
StatePublished - Nov 1 2011

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Materials Science(all)
  • Nuclear Energy and Engineering

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    Yun, D., Oaks, A. J., Chen, W. Y., Kirk, M. A., Rest, J., Insopov, Z. Z., Yacout, A. M., & Stubbins, J. F. (2011). Kr and Xe irradiations in lanthanum (La) doped ceria: Study at the high dose regime. Journal of Nuclear Materials, 418(1-3), 80-86. https://doi.org/10.1016/j.jnucmat.2011.08.005