Intermetallic Chalcogenide Atom Transfer and the Synthesis of 1,4-[(CH3C5H4)2Ti]2S4

C. Mark Bollnger; John E. Hoots; Thomas B. Rauchfuss

doi:10.1021/om00061a042

Intermetallic Chalcogenide Atom Transfer and the Synthesis of 1,4-[(CH₃C₅H₄)₂Ti]₂S₄

C. Mark Bollnger, John E. Hoots, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(C₆H₄R)₂TiE₅ (R = H, CH₃; E = S, Se) efficiently transfer a dichalcogenide fragment to [Ir(Ph₂PCH₂CH₂PPh₂)₂]Cl affording Ir^IIIE₂ complexes and in one case 1,4-[(C₅H₄CH₃)₂Ti]₂S ₄. The unique Ti₂S₄ heterocycle can also be prepared via the PBu₃ desulfurization of (C₅H₄CH₃)₂TiS₅.

Original language	English (US)
Pages (from-to)	223-225
Number of pages	3
Journal	Organometallics
Volume	1
Issue number	1
DOIs	https://doi.org/10.1021/om00061a042
State	Published - 1982

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00061a042

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title = "Intermetallic Chalcogenide Atom Transfer and the Synthesis of 1,4-[(CH3C5H4)2Ti]2S4",

abstract = "(C6H4R)2TiE5 (R = H, CH3; E = S, Se) efficiently transfer a dichalcogenide fragment to [Ir(Ph2PCH2CH2PPh2)2]Cl affording IrIIIE2 complexes and in one case 1,4-[(C5H4CH3)2Ti]2S 4. The unique Ti2S4 heterocycle can also be prepared via the PBu3 desulfurization of (C5H4CH3)2TiS5.",

author = "Bollnger, {C. Mark} and Hoots, {John E.} and Rauchfuss, {Thomas B.}",

year = "1982",

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volume = "1",

pages = "223--225",

journal = "Organometallics",

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publisher = "American Chemical Society",

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T1 - Intermetallic Chalcogenide Atom Transfer and the Synthesis of 1,4-[(CH3C5H4)2Ti]2S4

AU - Bollnger, C. Mark

AU - Hoots, John E.

AU - Rauchfuss, Thomas B.

PY - 1982

Y1 - 1982

N2 - (C6H4R)2TiE5 (R = H, CH3; E = S, Se) efficiently transfer a dichalcogenide fragment to [Ir(Ph2PCH2CH2PPh2)2]Cl affording IrIIIE2 complexes and in one case 1,4-[(C5H4CH3)2Ti]2S 4. The unique Ti2S4 heterocycle can also be prepared via the PBu3 desulfurization of (C5H4CH3)2TiS5.

AB - (C6H4R)2TiE5 (R = H, CH3; E = S, Se) efficiently transfer a dichalcogenide fragment to [Ir(Ph2PCH2CH2PPh2)2]Cl affording IrIIIE2 complexes and in one case 1,4-[(C5H4CH3)2Ti]2S 4. The unique Ti2S4 heterocycle can also be prepared via the PBu3 desulfurization of (C5H4CH3)2TiS5.

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