Intermetallic Chalcogenide Atom Transfer and the Synthesis of 1,4-[(CH3C5H4)2Ti]2S4

C. Mark Bollnger, John E. Hoots, Thomas B. Rauchfuss

Research output: Contribution to journalArticlepeer-review


(C6H4R)2TiE5 (R = H, CH3; E = S, Se) efficiently transfer a dichalcogenide fragment to [Ir(Ph2PCH2CH2PPh2)2]Cl affording IrIIIE2 complexes and in one case 1,4-[(C5H4CH3)2Ti]2S 4. The unique Ti2S4 heterocycle can also be prepared via the PBu3 desulfurization of (C5H4CH3)2TiS5.

Original languageEnglish (US)
Pages (from-to)223-225
Number of pages3
Issue number1
StatePublished - 1982

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry


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