Inter-Rydberg laser spectroscopy of ArKr

D. J. Kane, J. G. Eden

Research output: Contribution to journalArticlepeer-review

Abstract

Laser excitation spectroscopy of the ArKr heteronuclear molecule, studied in Ar/Kr gas mixtures over the interval 335 ≲λ≲ 485 nm, reveals a highly structured band peaking at 372 nm which is attributed to transitions of the excimer from the 5s 3Σ +(0-, 1) state (A 2Σ1/2+ core) to a shallow 0-, 1 potential having a B 2Π3/2 core and correlated with Ar(1S0) + Kr(6p) in the separated atom limit.

Original languageEnglish (US)
Pages (from-to)71-78
Number of pages8
JournalChemical Physics Letters
Volume144
Issue number1
DOIs
StatePublished - Feb 12 1988

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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