Independent control of rigidity and toughness of polymeric hydrogels

Hyun Joon Kong, Emma Wong, David J. Mooney

Research output: Contribution to journalArticlepeer-review

Abstract

Refined control over the mechanical properties of hydrogel-based materials has increased as these materials have found broader application. We investigated various aspects of gel cross-linking to independently regulate the elastic modulus (E) and toughness (W). Alginate hydrogels were chosen as a model system, since alginate can be gelled via ionic or covalent cross-linking, and its block structure dictates the structure of ionic cross-links. Increasing the density of covalent cross-links increased E but led to more brittle gels. In contrast, increasing the density of ionic cross-links and length of the blocks responsible for the cross-linking increased both E and W. Oscillatory shear measurements suggested that ionic cross-links and their length were important in dissipating the energy of deformation due to a partial and stepwise de-cross-linking. In contrast, covalently cross-linked gels underwent energy accumulation. This study demonstrates a novel approach to independently control different mechanical properties of gels.

Original languageEnglish (US)
Pages (from-to)4582-4588
Number of pages7
JournalMacromolecules
Volume36
Issue number12
DOIs
StatePublished - Jun 17 2003

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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