@article{997a1c4f8f1844ae8693af4e3ce23cab,
title = "Improved Quantum Yield in Geometrically Constrained Tetraphenylethylene-Based Metal-Organic Frameworks",
abstract = "Herein, we report the synthesis of a novel, tetraphenylethylene-based ligand for metal–organic frameworks (MOFs). Incorporation of this ligand into a Zn- or Eu-based MOF increased the quantum yield (QY) by almost 2.5× compared to the linker alone. Furthermore, the choice of guest solvent impacted the QY and solvatochromatic response. These shifts are consistent with solvent dielectric constant as well as molecular polarizability.",
author = "Stawiasz, {Katherine J} and Deneff, {Jacob I} and Reyes, {Raphael A} and Woods, {Toby John} and Shea-Rohwer, {Lauren E} and Valdez, {Nichole R} and Mark Rodriguez and Lawal, {Abdul Afeez} and Moore, {Jeffrey s.} and {Sava Gallis}, {Dorina F}",
note = "Funding Information: This research was supported by the Laboratory Directed Research and Development Program at Sandia National Laboratories. This article has been authored by an employee of National Technology & Engineering Solutions of Sandia, LLC under Contract No. DE-NA0003525 with the U.S. Department of Energy (DOE). The employee owns all right, title and interest in and to the article and is solely responsible for its contents. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this article or allow others to do so, for United States Government purposes. The DOE will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan https://www.energy.gov/downloads/doe-public-access-plan. The views expressed in this article do not necessarily represent the views of the U.S. Department of Energy or the United States Government. K. J. S. thanks the Department of Defense for an NDSEG fellowship. Funding Information: This research was supported by the Laboratory Directed Research and Development Program at Sandia National Laboratories. This article has been authored by an employee of National Technology & Engineering Solutions of Sandia, LLC under Contract No. DE-NA0003525 with the U.S. Department of Energy (DOE). The employee owns all right, title and interest in and to the article and is solely responsible for its contents. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this article or allow others to do so, for United States Government purposes. The DOE will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan https://www.energy.gov/downloads/doe-public-access-plan . The views expressed in this article do not necessarily represent the views of the U.S. Department of Energy or the United States Government. K. J. S. thanks the Department of Defense for an NDSEG fellowship. Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry",
year = "2023",
month = apr,
day = "17",
doi = "10.1039/D3CE00228D",
language = "English (US)",
volume = "25",
pages = "2701--2705",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "18",
}