II. Mathematical Model

Research output: Contribution to journalArticle

Abstract

A mathematical model of the current oscillations observed in the potentiostatic electrodissolution of a Cu rotating disk electrode is described and analyzed. The model predicts the conditions under which a CuCl film of constant thickness exists on the Cu surface, along with the conditions under which the film thickness and current density will be oscillatory (in some cases periodic) functions of time. The theoretical predictions are in excellent qualitative agreement with experimental results.

Original languageEnglish (US)
Pages (from-to)2159-2165
Number of pages7
JournalJournal of the Electrochemical Society
Volume132
Issue number9
DOIs
StatePublished - Sep 1985
Externally publishedYes

Fingerprint

Rotating disks
Film thickness
mathematical models
Current density
electrodissolution
Mathematical models
periodic functions
Electrodes
rotating disks
film thickness
current density
oscillations
electrodes
predictions

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Electrochemistry

Cite this

II. Mathematical Model. / Pearlstein, Arne J.

In: Journal of the Electrochemical Society, Vol. 132, No. 9, 09.1985, p. 2159-2165.

Research output: Contribution to journalArticle

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