Hydrophobic interactions in metalloporphyrin - Peptide complexes

D. L. Huffman, K. S. Suslick

Research output: Contribution to journalArticlepeer-review

Abstract

Synthetic heme-oligopeptide complexes of coproporphyrin-I-atoiron(III) have been prepared in aqueous solution, and their equilibrium formation constants have been determined by spectrophotometric titration. The presence of hydrophobic residues flanking the coordinated histidine dramatically increase peptide binding to the heme by more than 20 kJ/mol.

Original languageEnglish (US)
Pages (from-to)5418-5419
Number of pages2
JournalInorganic Chemistry
Volume39
Issue number24
DOIs
StatePublished - Nov 27 2000

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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