Hydroamination of alkenes

John F Hartwig; Zhijian Liu; Akihiro Takemiya

Hydroamination of alkenes

John F Hartwig (Inventor), Zhijian Liu (Inventor), Akihiro Takemiya (Inventor)

Research output: Patent

Abstract

A method includes reacting an amino group, a composition including rhodium and an organic ligand, and a substrate having structural formula (I) in a reaction mixture.R1 is an organic group including a sp3 carbon atom bonded to CA. R2 is selected from the group consisting of hydrogen, methyl, and an organic group including a sp3 carbon atom bonded to CA. R3 and R4 independently are selected from the group consisting of hydrogen, methyl, and an organic group including a sp3 carbon atom bonded to CB. The method further includes forming a hydroaminated product in the reaction mixture.

Original language	English (US)
U.S. patent number	8188302
Filing date	10/14/08
State	Published - May 29 2012

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title = "Hydroamination of alkenes",

abstract = "A method includes reacting an amino group, a composition including rhodium and an organic ligand, and a substrate having structural formula (I) in a reaction mixture.R1 is an organic group including a sp3 carbon atom bonded to CA. R2 is selected from the group consisting of hydrogen, methyl, and an organic group including a sp3 carbon atom bonded to CA. R3 and R4 independently are selected from the group consisting of hydrogen, methyl, and an organic group including a sp3 carbon atom bonded to CB. The method further includes forming a hydroaminated product in the reaction mixture.",

author = "Hartwig, {John F} and Zhijian Liu and Akihiro Takemiya",

note = "FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT The subject matter of this application may have been funded in part under a research grant from the National Institutes of Health, under Grant Number GM 55382. The U.S. Government may have rights in this invention.; 8188302",

year = "2012",

month = may,

day = "29",

language = "English (US)",

type = "Patent",

}

TY - PAT

T1 - Hydroamination of alkenes

AU - Hartwig, John F

AU - Liu, Zhijian

AU - Takemiya, Akihiro

N1 - FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT The subject matter of this application may have been funded in part under a research grant from the National Institutes of Health, under Grant Number GM 55382. The U.S. Government may have rights in this invention.

PY - 2012/5/29

Y1 - 2012/5/29

N2 - A method includes reacting an amino group, a composition including rhodium and an organic ligand, and a substrate having structural formula (I) in a reaction mixture.R1 is an organic group including a sp3 carbon atom bonded to CA. R2 is selected from the group consisting of hydrogen, methyl, and an organic group including a sp3 carbon atom bonded to CA. R3 and R4 independently are selected from the group consisting of hydrogen, methyl, and an organic group including a sp3 carbon atom bonded to CB. The method further includes forming a hydroaminated product in the reaction mixture.

AB - A method includes reacting an amino group, a composition including rhodium and an organic ligand, and a substrate having structural formula (I) in a reaction mixture.R1 is an organic group including a sp3 carbon atom bonded to CA. R2 is selected from the group consisting of hydrogen, methyl, and an organic group including a sp3 carbon atom bonded to CA. R3 and R4 independently are selected from the group consisting of hydrogen, methyl, and an organic group including a sp3 carbon atom bonded to CB. The method further includes forming a hydroaminated product in the reaction mixture.

M3 - Patent

M1 - 8188302

Y2 - 2008/10/14

ER -

Hydroamination of alkenes

Abstract

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