Highly conductive metallophthalocyanine assemblies. Structure, charge transport, and anisotropy in the metal-free molecular metal H2(Pc)I

T. Inabe; T. J. Marks; R. L. Burton; J. W. Lyding; W. J. McCarthy; C. R. Kannewurf; G. M. Reisner; F. H. Herbstein

doi:10.1016/0038-1098(85)90656-8

Highly conductive metallophthalocyanine assemblies. Structure, charge transport, and anisotropy in the metal-free molecular metal H₂(Pc)I

T. Inabe, T. J. Marks, R. L. Burton, J. W. Lyding, W. J. McCarthy, C. R. Kannewurf, G. M. Reisner, F. H. Herbstein

Abstract

That a metal ion is not required for high electrical conductivity is unequivocally demonstrated by structural, charge transport, optical, and magnetic characterization of the simplest phthalocyanine "molecular metal" H₂(Pc)I. The crystal structure consists of staggered H₂(Pc)^+0.33 units stacked at 3.251(3) Å intervals and parallel chains of I^-₃ counterions. At 300 K, σ_{{norm of matrix}} = 700 Ω^-1 cm^-1 and σ_{{norm of matrix}} σ⊥ > 500. At 15 K, σ_∼ reaches a maximum of ca. 4000 Ω^-1 cm^-1 and falls only to ca. 3500 Ω^{-1{norm of matrix}} cm^-1 at 1.5 K. Analysis of single crystal polarized specular reflectance data (ir to uv) yields ω_p = 6360(30) cm^-1 and a tight-binding bandwidth of 1.3(1) eV. The magnetic susceptibility is Pauli-like (X_S = 2.21(5) × 10^-4 emu mol^-1) except for a small, sample dependent Curie component.

Original language	English (US)
Pages (from-to)	501-504
Number of pages	4
Journal	Solid State Communications
Volume	54
Issue number	6
DOIs	https://doi.org/10.1016/0038-1098(85)90656-8
State	Published - May 1985
Externally published	Yes

Fingerprint

ASJC Scopus subject areas

Chemistry(all)
Condensed Matter Physics
Materials Chemistry

Cite this

Inabe, T., Marks, T. J., Burton, R. L., Lyding, J. W., McCarthy, W. J., Kannewurf, C. R., Reisner, G. M., & Herbstein, F. H. (1985). Highly conductive metallophthalocyanine assemblies. Structure, charge transport, and anisotropy in the metal-free molecular metal H₂(Pc)I. Solid State Communications, 54(6), 501-504. https://doi.org/10.1016/0038-1098(85)90656-8

Highly conductive metallophthalocyanine assemblies. Structure, charge transport, and anisotropy in the metal-free molecular metal H₂(Pc)I. / Inabe, T.; Marks, T. J.; Burton, R. L.; Lyding, J. W.; McCarthy, W. J.; Kannewurf, C. R.; Reisner, G. M.; Herbstein, F. H.

In: Solid State Communications, Vol. 54, No. 6, 05.1985, p. 501-504.

Research output: Contribution to journal › Article

@article{8e55c916f5534e78be584a9ca15861e0,

title = "Highly conductive metallophthalocyanine assemblies. Structure, charge transport, and anisotropy in the metal-free molecular metal H2(Pc)I",

abstract = "That a metal ion is not required for high electrical conductivity is unequivocally demonstrated by structural, charge transport, optical, and magnetic characterization of the simplest phthalocyanine {"}molecular metal{"} H2(Pc)I. The crystal structure consists of staggered H2(Pc)+0.33 units stacked at 3.251(3) {\AA} intervals and parallel chains of I-3 counterions. At 300 K, σ{norm of matrix} = 700 Ω-1 cm-1 and σ{norm of matrix} σ⊥ > 500. At 15 K, σ∼ reaches a maximum of ca. 4000 Ω-1 cm-1 and falls only to ca. 3500 Ω-1{norm of matrix} cm-1 at 1.5 K. Analysis of single crystal polarized specular reflectance data (ir to uv) yields ωp = 6360(30) cm-1 and a tight-binding bandwidth of 1.3(1) eV. The magnetic susceptibility is Pauli-like (XS = 2.21(5) × 10-4 emu mol-1) except for a small, sample dependent Curie component.",

author = "T. Inabe and Marks, {T. J.} and Burton, {R. L.} and Lyding, {J. W.} and McCarthy, {W. J.} and Kannewurf, {C. R.} and Reisner, {G. M.} and Herbstein, {F. H.}",

year = "1985",

month = may

doi = "10.1016/0038-1098(85)90656-8",

language = "English (US)",

volume = "54",

pages = "501--504",

journal = "Solid State Communications",

issn = "0038-1098",

publisher = "Elsevier Limited",

number = "6",

}

TY - JOUR

T1 - Highly conductive metallophthalocyanine assemblies. Structure, charge transport, and anisotropy in the metal-free molecular metal H2(Pc)I

AU - Inabe, T.

AU - Marks, T. J.

AU - Burton, R. L.

AU - Lyding, J. W.

AU - McCarthy, W. J.

AU - Kannewurf, C. R.

AU - Reisner, G. M.

AU - Herbstein, F. H.

PY - 1985/5

Y1 - 1985/5

N2 - That a metal ion is not required for high electrical conductivity is unequivocally demonstrated by structural, charge transport, optical, and magnetic characterization of the simplest phthalocyanine "molecular metal" H2(Pc)I. The crystal structure consists of staggered H2(Pc)+0.33 units stacked at 3.251(3) Å intervals and parallel chains of I-3 counterions. At 300 K, σ{norm of matrix} = 700 Ω-1 cm-1 and σ{norm of matrix} σ⊥ > 500. At 15 K, σ∼ reaches a maximum of ca. 4000 Ω-1 cm-1 and falls only to ca. 3500 Ω-1{norm of matrix} cm-1 at 1.5 K. Analysis of single crystal polarized specular reflectance data (ir to uv) yields ωp = 6360(30) cm-1 and a tight-binding bandwidth of 1.3(1) eV. The magnetic susceptibility is Pauli-like (XS = 2.21(5) × 10-4 emu mol-1) except for a small, sample dependent Curie component.

AB - That a metal ion is not required for high electrical conductivity is unequivocally demonstrated by structural, charge transport, optical, and magnetic characterization of the simplest phthalocyanine "molecular metal" H2(Pc)I. The crystal structure consists of staggered H2(Pc)+0.33 units stacked at 3.251(3) Å intervals and parallel chains of I-3 counterions. At 300 K, σ{norm of matrix} = 700 Ω-1 cm-1 and σ{norm of matrix} σ⊥ > 500. At 15 K, σ∼ reaches a maximum of ca. 4000 Ω-1 cm-1 and falls only to ca. 3500 Ω-1{norm of matrix} cm-1 at 1.5 K. Analysis of single crystal polarized specular reflectance data (ir to uv) yields ωp = 6360(30) cm-1 and a tight-binding bandwidth of 1.3(1) eV. The magnetic susceptibility is Pauli-like (XS = 2.21(5) × 10-4 emu mol-1) except for a small, sample dependent Curie component.

UR - http://www.scopus.com/inward/record.url?scp=0022062473&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0022062473&partnerID=8YFLogxK

U2 - 10.1016/0038-1098(85)90656-8

DO - 10.1016/0038-1098(85)90656-8

M3 - Article

AN - SCOPUS:0022062473

VL - 54

SP - 501

EP - 504

JO - Solid State Communications

JF - Solid State Communications

SN - 0038-1098

IS - 6

ER -

Access to Document

10.1016/0038-1098(85)90656-8