High temperature continuous flow synthesis of CdSe/CdS/ZnS, CdS/ZnS, and CdSeS/ZnS nanocrystals

Matt S. Naughton, Vivek Kumar, Yolanda Bonita, Kishori Deshpande, Paul J.A. Kenis

Research output: Contribution to journalArticle

Abstract

Continuous flow reactors show great promise for large-scale synthesis of quantum dots. Here, we discuss results for the synthesis of multi-layered Cd-based hybrid nanocrystals-CdSe/CdS/ZnS, CdS/ZnS, and CdSeS/ZnS-in a continuous flow reactor. The simple reactor design and liquid-phase chemistry obviate the need for preheating or in-line mixing, and the chosen reactor dimensions and operating conditions allow for high flow rates (∼10 mL min-1). Additionally, the simple reactor design is well suited for scale-up. The CdSe/CdS/ZnS particles synthesized at elevated temperatures in the reactor exhibit quantum yields of over 60% at longer wavelengths (red region). The shell growth for these particles is conducted without the need for complex dropwise addition or SILAR shell growth procedures used in batch reactors. CdS-based particles were shown to have a higher performance when using octadecene-S instead of TOP-S, which improved the quality of shell growth. In addition, stoichiometric synthesis of the alternate CdSeS/ZnS alloy particles was conducted, removing the need for a large excess of S to offset the lower S reactivity. CdSeS/ZnS alloy nanoparticles exhibit quantum yields of about 50% in the intermediate wavelength range (500-600 nm).

Original languageEnglish (US)
Pages (from-to)15895-15903
Number of pages9
JournalNanoscale
Volume7
Issue number38
DOIs
StatePublished - Oct 14 2015

ASJC Scopus subject areas

  • Materials Science(all)

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