High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls

Eric Oldfield, Max A. Keniry, Sumio Shinoda, Suzanne Schramm, Theodore L. Brown, H. S. Gutowsky

Research output: Contribution to journalArticle

Abstract

We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the 17O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the 17O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C17O groups may be detected.

Original languageEnglish (US)
Pages (from-to)791-793
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number12
DOIs
StatePublished - Jan 1 1985

ASJC Scopus subject areas

  • Molecular Medicine

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