We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the 17O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the 17O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C17O groups may be detected.
|Original language||English (US)|
|Number of pages||3|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - 1985|
ASJC Scopus subject areas
- Molecular Medicine