High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls

Eric Oldfield; Max A. Keniry; Sumio Shinoda; Suzanne Schramm; Theodore L. Brown; H. S. Gutowsky

doi:10.1039/c39850000791

High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls

Eric Oldfield, Max A. Keniry, Sumio Shinoda, Suzanne Schramm, Theodore L. Brown, H. S. Gutowsky

Chemistry

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Abstract

We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the ¹⁷O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the ¹⁷O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C¹⁷O groups may be detected.

Original language	English (US)
Pages (from-to)	791-793
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/c39850000791
State	Published - 1985

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Molecular Medicine

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10.1039/c39850000791

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title = "High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls",

abstract = "We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the 17O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the 17O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C17O groups may be detected.",

author = "Eric Oldfield and Keniry, {Max A.} and Sumio Shinoda and Suzanne Schramm and Brown, {Theodore L.} and Gutowsky, {H. S.}",

year = "1985",

doi = "10.1039/c39850000791",

language = "English (US)",

pages = "791--793",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "12",

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T1 - High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls

AU - Oldfield, Eric

AU - Keniry, Max A.

AU - Shinoda, Sumio

AU - Schramm, Suzanne

AU - Brown, Theodore L.

AU - Gutowsky, H. S.

PY - 1985

Y1 - 1985

N2 - We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the 17O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the 17O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C17O groups may be detected.

AB - We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the 17O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the 17O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C17O groups may be detected.

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JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls

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