High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls

Eric Oldfield, Max A. Keniry, Sumio Shinoda, Suzanne Schramm, Theodore L. Brown, H. S. Gutowsky

Research output: Contribution to journalArticle

Abstract

We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the 17O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the 17O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C17O groups may be detected.

Original languageEnglish (US)
Pages (from-to)791-793
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number12
DOIs
StatePublished - Jan 1 1985

Fingerprint

Anisotropy
Chemical shift
Nuclear magnetic resonance spectroscopy
Transition metals
Tensors
Magnetic Resonance Spectroscopy
Metals
Oxygen

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls. / Oldfield, Eric; Keniry, Max A.; Shinoda, Sumio; Schramm, Suzanne; Brown, Theodore L.; Gutowsky, H. S.

In: Journal of the Chemical Society, Chemical Communications, No. 12, 01.01.1985, p. 791-793.

Research output: Contribution to journalArticle

Oldfield, Eric ; Keniry, Max A. ; Shinoda, Sumio ; Schramm, Suzanne ; Brown, Theodore L. ; Gutowsky, H. S. / High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls. In: Journal of the Chemical Society, Chemical Communications. 1985 ; No. 12. pp. 791-793.
@article{2f573885d9f24fa4ad8f5b80e1e2192a,
title = "High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls",
abstract = "We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the 17O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the 17O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C17O groups may be detected.",
author = "Eric Oldfield and Keniry, {Max A.} and Sumio Shinoda and Suzanne Schramm and Brown, {Theodore L.} and Gutowsky, {H. S.}",
year = "1985",
month = "1",
day = "1",
doi = "10.1039/c39850000791",
language = "English (US)",
pages = "791--793",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "12",

}

TY - JOUR

T1 - High-resolution solid-state oxygen-17 nuclear magnetic resonance spectroscopy of transition metal carbonyls

AU - Oldfield, Eric

AU - Keniry, Max A.

AU - Shinoda, Sumio

AU - Schramm, Suzanne

AU - Brown, Theodore L.

AU - Gutowsky, H. S.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the 17O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the 17O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C17O groups may be detected.

AB - We have obtained the first high-resolution solid-state oxygen-17 n.m.r. spectra of a series of transition metal carbonyls and the results indicate that the principal elements of the 17O chemical shift tensors may be determined, that the anisotropies are very large (Δδ ca. 600-700 p.p.m.) while the 17O quadrupole coupling constants are very small (ca. 1 MHz), and that magnetically nonequivalent C17O groups may be detected.

UR - http://www.scopus.com/inward/record.url?scp=0006144181&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0006144181&partnerID=8YFLogxK

U2 - 10.1039/c39850000791

DO - 10.1039/c39850000791

M3 - Article

AN - SCOPUS:0006144181

SP - 791

EP - 793

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 12

ER -