@article{cd68ec9cd3c040bda99d1f50381a47de,
title = "High-resolution solid-state N.M.R. spectra of quadrupolar nuclei: Magic-angle and off-axis spinning of vansdhaum-51 (I= 7/2) in sodium and ammonium metavanadates",
abstract = "We report the first observation of high-resolution solid-state n.m.r. spectra of the quadrupolar transition metal nucleus vanadium-51, in NH4[51VO3] and Na[51VO3], by means of rapid {\textquoteleft}magic-angle{\textquoteright} and {\textquoteleft}off-axis{\textquoteright} spinning experiments; the results indicate the general feasibility of obtaining high-resolution solid-state n.m.r. spectra of quadrupolar nuclei having large chemical shift (ca. l03 p.p.m.) and quadrupole (e2qQ/h ca. 3-5 M Hz) interactions.",
author = "Eric Oldfield and Kinsey, {Robert A.} and Bernard Montez and Tane Ray and Smith, {Karen Ann}",
note = "Funding Information: is a U.S.P.H.S. Research Career Development Awardee. This work was supported by grants from the N.I.H., N.S.F., American Heart Association, Illinois Heart Associa- tion, and the U.1-N.S.F. Regional Instrumentation Facility. Received, 8th September I981; Com. 1073 J. CHEM. SOC., CHEM. COMMUN., 1982 References 1 D. Muller, W. Gessner, H.-J. Behrens, and G. Scheler, Chem. Phys. Lett., 1981, 79, 59. D. Freude and H.-J. Behrens, Cryst. Res. Tech., 1981, 16, K36. M. D. Meadows, K. A. Smith, R. A. Kinsey, T. M. Rothgeb, R. P. Skarjune, and E. Oldfield, Proc. Natl. Acad. Sci. U.S.A., 1982, in the press. E. Oldfield, S. Schramm, M. D. Meadows, K. A. Smith, R. A. Kinsey, and J. Ackerman, J. Am. Chem. Suc., 1982, in the press. E. Kundla, A. Samoson, and E. Lippmaa, Chem. Phys. Lett., 1981, 83,229. 6 D. J.' Burton and R. K. Harris, following communication. 7 E. R. Andrew, Arch. Sci.,1959, 12, 103. 8 M. M. Maricq and J. S. Waugh, J. Chem. Phys., 1979, 70, 3300. 9 J. F. Baugher, P. C. Taylor, T. Oja, and P. J. Bray, J. Chem. Phys., 1969, 50, 4914. 10 S. L. Segel and R. B. Creel, Can. J. Phys., 1970, 48,2673. 11 J. Herzfeld and A. E. Berger, J. Chern. Phys., 1980, 73, 6021. 12 W. P. Aue, D, J. Ruben, and R. G. Griffin, J. Magn. Reson., 1981, 43,472.",
year = "1982",
doi = "10.1039/C39820000254",
language = "English (US)",
pages = "254--256",
journal = "Journal of the Chemical Society - Series Chemical Communications",
issn = "0022-4936",
publisher = "Royal Society of Chemistry",
number = "4",
}