High-resolution solid-state N.M.R. spectra of quadrupolar nuclei: Magic-angle and off-axis spinning of vansdhaum-51 (I= 7/2) in sodium and ammonium metavanadates

Eric Oldfield, Robert A. Kinsey, Bernard Montez, Tane Ray, Karen Ann Smith

Research output: Contribution to journalArticlepeer-review

Abstract

We report the first observation of high-resolution solid-state n.m.r. spectra of the quadrupolar transition metal nucleus vanadium-51, in NH4[51VO3] and Na[51VO3], by means of rapid ‘magic-angle’ and ‘off-axis’ spinning experiments; the results indicate the general feasibility of obtaining high-resolution solid-state n.m.r. spectra of quadrupolar nuclei having large chemical shift (ca. l03 p.p.m.) and quadrupole (e2qQ/h ca. 3-5 M Hz) interactions.

Original languageEnglish (US)
Pages (from-to)254-256
Number of pages3
JournalJournal of the Chemical Society - Series Chemical Communications
Issue number4
DOIs
StatePublished - 1982

ASJC Scopus subject areas

  • Molecular Medicine

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