High-resolution broadband N2coherent anti-Stokes Raman spectroscopy: Comparison of measurements for conventional and modeless broadband dye lasers

Joel P. Kuehner, Mark A. Woodmansee, Robert P. Lucht, J. Craig Dutton

Research output: Contribution to journalArticlepeer-review


We have performed high-resolution N2coherent anti-Stokes Raman spectroscopy (CARS) measurements using a modeless dye laser (MDL) as the Stokes beam source to determine the effects of a reduction in mode noise on the accuracy and precision of the method. These results are compared with previous research that employed a conventional broadband dye laser (CBDL) as the Stokes beam source. A new spectral-fitting procedure was developed to avoid starting-point bias in the least-squares fitting results, which possibly had altered the previous measurements. Single-shot measurements of pressure were performed in a static-pressure vessel over the range of 0.1–4.0 atm to examine the pressure sensitivity of the technique. The precision of these measurements is a measure of the baseline noise level of the system, which sets the detection limit for flow-field pressure fluctuations. Centerline measurements of pressure and temperature in an underexpanded jet (Mj= 1.85) were also used to determine the performance of the technique in a compressible flow field. Our study represents the first known application, to our knowledge, of a MDL CARS system in a low-temperature, low-pressure supersonic environment. Improvements in accuracy for mean single-shot measurements and increased precision were found for pressure vessel conditions above 1.0 atm. For subatmospheric pressure vessel conditions (0.1–1.0 atm) and the underexpanded jet measurements, there was a decrease in accuracy and precision compared with the CBDL results. A comparison with the CBDL study is included, along with a discussion of the MDL system behavior.

Original languageEnglish (US)
Pages (from-to)6757-6767
Number of pages11
JournalApplied Optics
Issue number33
StatePublished - Nov 20 2003

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Engineering (miscellaneous)
  • Electrical and Electronic Engineering


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