Heterobimetallic Cooperativity in the Reduction of Methyl Isocyanide by (C5H5)2W(SH)2

Thomas B. Rauchfuss; Charles J. Ruffing

doi:10.1021/om00062a029

Heterobimetallic Cooperativity in the Reduction of Methyl Isocyanide by (C₅H₅)₂W(SH)₂

Thomas B. Rauchfuss, Charles J. Ruffing

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The metaliodithiol (C₅H₅)₂W(SH)₂ reacts with [Pd(CH₃NC)₂(Ph₂PCH₂CH₂PPh₂)](PF₆)₂ to form the N-methyldithiocarbamate [(C₅H₅)₂WS₂CN(H)CH₃]PF₆ (3) via a novel hydrogen-transfer reaction. An independent synthesis of 3 and (C₅H₅)₂W derivatives of other sulfur ligands is also reported.

Original language	English (US)
Pages (from-to)	400-401
Number of pages	2
Journal	Organometallics
Volume	1
Issue number	2
DOIs	https://doi.org/10.1021/om00062a029
State	Published - 1982

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00062a029

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Cite this

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title = "Heterobimetallic Cooperativity in the Reduction of Methyl Isocyanide by (C5H5)2W(SH)2",

abstract = "The metaliodithiol (C5H5)2W(SH)2 reacts with [Pd(CH3NC)2(Ph2PCH2CH2PPh2)](PF6)2 to form the N-methyldithiocarbamate [(C5H5)2WS2CN(H)CH3]PF6 (3) via a novel hydrogen-transfer reaction. An independent synthesis of 3 and (C5H5)2W derivatives of other sulfur ligands is also reported.",

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year = "1982",

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journal = "Organometallics",

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AU - Rauchfuss, Thomas B.

AU - Ruffing, Charles J.

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Y1 - 1982

N2 - The metaliodithiol (C5H5)2W(SH)2 reacts with [Pd(CH3NC)2(Ph2PCH2CH2PPh2)](PF6)2 to form the N-methyldithiocarbamate [(C5H5)2WS2CN(H)CH3]PF6 (3) via a novel hydrogen-transfer reaction. An independent synthesis of 3 and (C5H5)2W derivatives of other sulfur ligands is also reported.

AB - The metaliodithiol (C5H5)2W(SH)2 reacts with [Pd(CH3NC)2(Ph2PCH2CH2PPh2)](PF6)2 to form the N-methyldithiocarbamate [(C5H5)2WS2CN(H)CH3]PF6 (3) via a novel hydrogen-transfer reaction. An independent synthesis of 3 and (C5H5)2W derivatives of other sulfur ligands is also reported.

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