Glycerol tri-ester derivatives as diluent to improve low temperature properties of vegetable oils

Shailesh N. Shah, Bryan R. Moser, Brajendra K. Sharma

Research output: Contribution to journalArticlepeer-review

Abstract

The large-scale production of biodiesel has led to a surplus of glycerol, so the new commercial uses of this co-product are being sought. Twenty-three vegetable oils were screened using glycerol tris(2-ethylhexanoate) [GTEH] as a diluent to improve the low temperature properties. Epoxidized soybean oil (ESBO) and palm oil (PO) have shown maximum improvements in pour points (PPs) upon addition of GTEH as diluent. Maximum improvements in PP of 16 and 9°C were observed in ESBO and PO, with 50 and 25 vol % GTEH, respectively. The five vegetable oils (ESBO, PO, sunflower oil (SFO), mid-oleic SFO, and camelina oil (CO)) with maximum improvement in PP were studied further at lower concentrations of GTEH. The variation in PP response to GTEH is attributed to variations in the fatty acid compositions of the vegetable oils. This study demonstrates the viability of using GTEH as diluents with vegetable oils to improve their low temperature properties.

Original languageEnglish (US)
Pages (from-to)450-463
Number of pages14
JournalASTM Special Technical Publication
Volume1477
StatePublished - 2011
Externally publishedYes

Keywords

  • Biodiesel
  • Diluents
  • Glycerol
  • Low temperature
  • Lubricant
  • Pour point
  • Vegetable oils

ASJC Scopus subject areas

  • Materials Science(all)

Fingerprint Dive into the research topics of 'Glycerol tri-ester derivatives as diluent to improve low temperature properties of vegetable oils'. Together they form a unique fingerprint.

Cite this