Giant Organometallic Networks Derived from Ferrocenepolysulfides

Collin P. Galloway, Thomas B. Rauchfuss

Research output: Contribution to journalArticlepeer-review


Desulfurization with tributylphosphane converts the ferrocenepolysulfide 1 into three‐dimensional network polymers. These consist of ferrocene subunits interconnected by oligosulfide crosslinks. Gel permeation chromatography on an analogous polymerized alkyl derivative of 1 indicates molecular weights in excess of 106 Da. •=Fe. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)1319-1321
Number of pages3
JournalAngewandte Chemie International Edition in English
Issue number9
StatePublished - Sep 1993

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry


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