Fourteen-Electron Organoiron Species: Synthesis and Characterization of High-Spin Iron (II) Alkyls and the Crystal Structure of the Benzyl Derivative Fe(CH₂C₆H₄CH₃)₂(dippe)

Keyphrases

• Alkyl 100%
• Higher Spin 100%
• Benzyl Derivatives 100%
• Organoiron 100%
• Fe-P 60%
• FEniCS 40%
• Electron Counting 40%
• Four-coordinate 40%
• Magnetic Moment 20%
• X-ray Crystallography 20%
• Stoichiometry 20%
• Monoclinic 20%
• Catalytic Activity 20%
• Ethane 20%
• NMR Spectra 20%
• Alkylation 20%
• X-ray Crystal Structure 20%
• Low Spin 20%
• P-distance 20%
• D-orbital 20%
• Steric Effect 20%
• Alkyl Group 20%
• Phosphine Complexes 20%
• Agostic Interactions 20%
• Crystallographic Data 20%
• Contact Shift 20%
• Insertion Technique 20%
• Moment Features 20%
• C-distance 20%
• Dialkylmagnesium 20%
• Grignard 20%
• Distorted Tetrahedral Geometry 20%
• Olefin Insertion 20%
• Ziegler-Natta 20%
• Benzylic Position 20%

Chemistry

• Crystal Structure 100%
• Magnetic Moment 50%
• Reaction Stoichiometry 50%
• Monoclinic Space Group 50%
• NMR Spectrum 50%
• Alkene 50%
• Iron Complex 50%
• Alkyl Group 50%
• Steric Effect 50%