Forced chemical mixing in immiscible alloys during severe plastic deformation at elevated temperatures

Nhon Q. Vo, Samson Odunuga, Pascal Bellon, Robert S. Averback

Research output: Contribution to journalArticlepeer-review

Abstract

The forced chemical mixing of atoms in model immiscible alloys during severe plastic deformation (SPD) has been investigated as a function of temperature and the heat of mixing using molecular dynamics computer simulations. At low temperatures, A75B25 alloys form solid solutions during SPD for heats of mixing less than ∼20 kJ mol-1, but tend to phase separate at larger values. At high temperatures these alloys show more extensive precipitation, with the precipitate morphology dependent on the heat of mixing. Analysis of the high-temperature mixing kinetics reveals that the precipitation process involves two separate mechanisms. The first derives from long-range diffusion mediated by shear-induced vacancies, while the second is due to local rearrangements of atoms induced by the forced mixing of atoms.

Original languageEnglish (US)
Pages (from-to)3012-3019
Number of pages8
JournalActa Materialia
Volume57
Issue number10
DOIs
StatePublished - Jun 2009

Keywords

  • Forced mixing
  • Mechanical alloying
  • Molecular dynamics
  • Severe plastic deformation

ASJC Scopus subject areas

  • Ceramics and Composites
  • Metals and Alloys
  • Polymers and Plastics
  • Electronic, Optical and Magnetic Materials

Fingerprint

Dive into the research topics of 'Forced chemical mixing in immiscible alloys during severe plastic deformation at elevated temperatures'. Together they form a unique fingerprint.

Cite this