Flow-enhanced solution printing of all-polymer solar cells

Ying Diao, Yan Zhou, Tadanori Kurosawa, Leo Shaw, Cheng Wang, Steve Park, Yikun Guo, Julia A. Reinspach, Kevin Gu, Xiaodan Gu, Benjamin C.K. Tee, Changhyun Pang, Hongping Yan, Dahui Zhao, Michael F. Toney, Stefan C.B. Mannsfeld, Zhenan Bao

Research output: Contribution to journalArticlepeer-review

Abstract

Morphology control of solution coated solar cell materials presents a key challenge limiting their device performance and commercial viability. Here we present a new concept for controlling phase separation during solution printing using an all-polymer bulk heterojunction solar cell as a model system. The key aspect of our method lies in the design of fluid flow using a microstructured printing blade, on the basis of the hypothesis of flow-induced polymer crystallization. Our flow design resulted in a ∼90% increase in the donor thin film crystallinity and reduced microphase separated donor and acceptor domain sizes. The improved morphology enhanced all metrics of solar cell device performance across various printing conditions, specifically leading to higher short-circuit current, fill factor, open circuit voltage and significantly reduced device-to-device variation. We expect our design concept to have broad applications beyond all-polymer solar cells because of its simplicity and versatility.

Original languageEnglish (US)
Article number7955
JournalNature communications
Volume6
DOIs
StatePublished - Aug 12 2015

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

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