[FeFe]-hydrogenase models and hydrogen: Oxidative addition of dihydrogen and silanes

Zachariah M. Heiden; Giuseppe Zampella; Luca De Gioia; Thomas B. Rauchfuss

doi:10.1002/anie.200804400

[FeFe]-hydrogenase models and hydrogen: Oxidative addition of dihydrogen and silanes

Zachariah M. Heiden, Giuseppe Zampella, Luca De Gioia, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) Super model: Diiron dithiolates exist in nature in [FeFe]-hydrogenase, for the purpose of making or oxidizing molecular hydrogen. Evidence for how H₂ interacts with diiron complexes has been realized using model diiron dithiolato carbonyl complexes. The pathway for this interaction has been elucidated computationally as well as synthetically, by using silanes in place of H₂.

Original language	English (US)
Pages (from-to)	9756-9759
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	50
DOIs	https://doi.org/10.1002/anie.200804400
State	Published - Dec 1 2008

Keywords

Agostic interactions
Hydrogen
Hydrogenase
Iron
Silanes

ASJC Scopus subject areas

Chemistry(all)
Catalysis

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10.1002/anie.200804400

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abstract = "(Chemical Equation Presented) Super model: Diiron dithiolates exist in nature in [FeFe]-hydrogenase, for the purpose of making or oxidizing molecular hydrogen. Evidence for how H2 interacts with diiron complexes has been realized using model diiron dithiolato carbonyl complexes. The pathway for this interaction has been elucidated computationally as well as synthetically, by using silanes in place of H2.",

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AU - De Gioia, Luca

AU - Rauchfuss, Thomas B.

PY - 2008/12/1

Y1 - 2008/12/1

N2 - (Chemical Equation Presented) Super model: Diiron dithiolates exist in nature in [FeFe]-hydrogenase, for the purpose of making or oxidizing molecular hydrogen. Evidence for how H2 interacts with diiron complexes has been realized using model diiron dithiolato carbonyl complexes. The pathway for this interaction has been elucidated computationally as well as synthetically, by using silanes in place of H2.

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KW - Agostic interactions

KW - Hydrogen

KW - Hydrogenase

KW - Iron

KW - Silanes

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[FeFe]-hydrogenase models and hydrogen: Oxidative addition of dihydrogen and silanes

Abstract

Keywords

ASJC Scopus subject areas

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