Extract Nitrogen-Containing Compounds in Biocrude Oil Converted from Wet Biowaste via Hydrothermal Liquefaction

Wan Ting Chen, Liyin Tang, Wanyi Qian, Karalyn Scheppe, Ken Nair, Zhenwei Wu, Chao Gai, Peng Zhang, Yuanhui Zhang

Research output: Contribution to journalArticlepeer-review

Abstract

This study demonstrates that water can serve as a green solvent to achieve denitrogenation of biocrude oil converted from wet biowaste via hydrothermal liquefaction (HTL) under previously determined optimal reaction conditions (300°C with a 1 h reaction time for swine manure and Chlorella; 300°C with a 0.5 h reaction time for Spirulina). It was hypothesized that water could extract relatively polar chemicals, such as some of the nitrogen-containing compounds, from HTL biocrude oil. This hypothesis was examined by different extraction techniques using water as a solvent to HTL biocrude oil converted from swine manure (SM) and low-lipid algae. The water solubilities of biocrude oil and product yields (water extract, biocrude oil, solid residue, and aqueous and gas products) were measured. Compared to that of the biocrude oil without extraction by water, the nitrogen content of biocrude oil converted from SM decreased from 4.32 to 3.23%. Gas chromatography-mass spectrometry (GC-MS) analyses of treated biocrude oil and water extract demonstrated that water can extract nitrogen-containing compounds and separate fatty acid derivatives that were originally in biocrude oil. When an ultrasonically assisted extraction by water was conducted, the nitrogen content in algal biocrude oil decreased from 6.83 to 5.75% with improved carbon and hydrogen content. In addition, GC-MS analyses of treated biocrude oil and water extract suggest that fatty acid derivatives may behave like surfactants and help in emulsifying nitrogen-containing compounds into water.

Original languageEnglish (US)
Pages (from-to)2182-2190
Number of pages9
JournalACS Sustainable Chemistry and Engineering
Volume4
Issue number4
DOIs
StatePublished - Apr 4 2016

Keywords

  • Denitrogenation
  • HTL biocrude oil
  • Value-added chemicals
  • Water
  • Wet biowaste

ASJC Scopus subject areas

  • General Chemistry
  • Environmental Chemistry
  • General Chemical Engineering
  • Renewable Energy, Sustainability and the Environment

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