Evidence for the existence of a terminal imidoscandium compound: Intermolecular C-H activation and complexation reactions with the transient Sc=NAr species

Jennifer Scott; Falguni Basuli; Alison R. Fout; John C. Huffman; Daniel J. Mindiola

doi:10.1002/anie.200803325

Evidence for the existence of a terminal imidoscandium compound: Intermolecular C-H activation and complexation reactions with the transient Sc=NAr species

Jennifer Scott, Falguni Basuli, Alison R. Fout, John C. Huffman, Daniel J. Mindiola

Research output: Contribution to journal › Article › peer-review

Abstract

Don't blink or you'll miss it: A transient imidoscandium complex (see scheme) can be generated by several routes. The imido ligand can activate the C-H bond in pyridine and benzene, and it can be complexed with Al(CH ₃)₃ to yield an imide zwitterion. A combination of isotopic labeling, reactivity, and theoretical studies strongly endorse formation of a terminal imido ligand at scandium. (Chemical Equation Presented)

Original language	English (US)
Pages (from-to)	8502-8505
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	44
DOIs	https://doi.org/10.1002/anie.200803325
State	Published - Oct 20 2008
Externally published	Yes

Keywords

Abstraction
C-H activation
Imido ligands
Metalation
Scandium

ASJC Scopus subject areas

Catalysis
General Chemistry

Online availability

10.1002/anie.200803325

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Evidence for the existence of a terminal imidoscandium compound: Intermolecular C-H activation and complexation reactions with the transient Sc=NAr species. / Scott, Jennifer; Basuli, Falguni; Fout, Alison R. et al.
In: Angewandte Chemie - International Edition, Vol. 47, No. 44, 20.10.2008, p. 8502-8505.

Research output: Contribution to journal › Article › peer-review

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Evidence for the existence of a terminal imidoscandium compound: Intermolecular C-H activation and complexation reactions with the transient Sc=NAr species

Abstract

Keywords

ASJC Scopus subject areas

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