EVIDENCE FOR CONDUCTION ELECTRON-INTRAMOLECULAR VIBRATION INTERACTION IN A PLATINUM CHAIN SALT.

David B. Tanner; L. H. Greene; A. J. Epstein; Joel S. Miller

doi:10.1080/00268948208072565

EVIDENCE FOR CONDUCTION ELECTRON-INTRAMOLECULAR VIBRATION INTERACTION IN A PLATINUM CHAIN SALT.

David B. Tanner, L. H. Greene, A. J. Epstein, Joel S. Miller

Physics

Research output: Contribution to journal › Conference article › peer-review

Abstract

Polarized reflectance measurements revealed a deep indentation in the chain-axis reflectance at a substantially lower frequency than the ordinary (C EQUVLNT N) stretching frequency. The frequency-dependent conductivity had a deep antiresonance at about the same frequency. This structure was attributed to a phase-phonon mode of the coupled electron-intramolecular vibration system. These data provide the first direct evidence for the importance of the interaction of the conduction electrons with molecular vibrations in a metal chain compound.

Original language	English (US)
Pages (from-to)	189-196
Number of pages	8
Journal	Molecular crystals and liquid crystals
Volume	81
Issue number	1-4
DOIs	https://doi.org/10.1080/00268948208072565
State	Published - Jan 1 1982
Event	Proc of the Int Conf on Low-Dimens Conduct, Pt C - Boulder, Colo, USA Duration: Aug 9 1981 → Aug 14 1981

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1080/00268948208072565

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title = "EVIDENCE FOR CONDUCTION ELECTRON-INTRAMOLECULAR VIBRATION INTERACTION IN A PLATINUM CHAIN SALT.",

abstract = "Polarized reflectance measurements revealed a deep indentation in the chain-axis reflectance at a substantially lower frequency than the ordinary (C EQUVLNT N) stretching frequency. The frequency-dependent conductivity had a deep antiresonance at about the same frequency. This structure was attributed to a phase-phonon mode of the coupled electron-intramolecular vibration system. These data provide the first direct evidence for the importance of the interaction of the conduction electrons with molecular vibrations in a metal chain compound.",

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AU - Tanner, David B.

AU - Greene, L. H.

AU - Epstein, A. J.

AU - Miller, Joel S.

PY - 1982/1/1

Y1 - 1982/1/1

N2 - Polarized reflectance measurements revealed a deep indentation in the chain-axis reflectance at a substantially lower frequency than the ordinary (C EQUVLNT N) stretching frequency. The frequency-dependent conductivity had a deep antiresonance at about the same frequency. This structure was attributed to a phase-phonon mode of the coupled electron-intramolecular vibration system. These data provide the first direct evidence for the importance of the interaction of the conduction electrons with molecular vibrations in a metal chain compound.

AB - Polarized reflectance measurements revealed a deep indentation in the chain-axis reflectance at a substantially lower frequency than the ordinary (C EQUVLNT N) stretching frequency. The frequency-dependent conductivity had a deep antiresonance at about the same frequency. This structure was attributed to a phase-phonon mode of the coupled electron-intramolecular vibration system. These data provide the first direct evidence for the importance of the interaction of the conduction electrons with molecular vibrations in a metal chain compound.

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SN - 1542-1406

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T2 - Proc of the Int Conf on Low-Dimens Conduct, Pt C

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ER -

EVIDENCE FOR CONDUCTION ELECTRON-INTRAMOLECULAR VIBRATION INTERACTION IN A PLATINUM CHAIN SALT.

Abstract

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