Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

Thao M. Xiong, Edzna S. Garcia, Junfeng Chen, Lingyang Zhu, Ariale J. Alzona, Steven C. Zimmerman

Research output: Contribution to journalArticlepeer-review

Abstract

We report a modular approach in which a noncovalently cross-linked single chain nanoparticle (SCNP) selectively binds catalyst "cofactors"and substrates to increase both the catalytic activity of a Cu-catalyzed alkyne-azide cycloaddition reaction and the Ru-catalyzed cleavage of allylcarbamate groups compared to the free catalysts. This journal is

Original languageEnglish (US)
Pages (from-to)985-988
Number of pages4
JournalChemical Communications
Volume58
Issue number7
DOIs
StatePublished - Jan 21 2022

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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