Entropic barriers, activated hopping, and the glass transition in colloidal suspensions were investigated. Thermal fluctuations were included via a random force which restored ergodicity through activated barrier hopping. Results showed multiple connections between thermodynamics, short-time dynamics in the nearly localized state, and long-time relaxation by entropic barrier crossing.
|Original language||English (US)|
|Number of pages||16|
|Journal||Journal of Chemical Physics|
|State||Published - Jul 8 2003|
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry