Enhancing capacitive deionization performance with charged structural polysaccharide electrode binders

Martin Kim, Martina del Cerro, Steven Hand, Roland Cusick

Research output: Contribution to journalArticle

Abstract

Capacitive deionization (CDI) performance, as measured by salt adsorption capacity (SAC) and energy normalized adsorption of salt (ENAS), is frequently limited by anion repulsion at the positive electrode. In this work, we investigate the ability to prevent co-ion repulsion by increasing complementary fixed charged within the electrode macropores by binding composite CDI electrodes with the ionically charged structural polysaccharides chitosan and carboxymethyl cellulose. When employing asymmetrically charged electrode binders, co-ion repulsion was prevented, resulting in SAC and ENAS values that were three times greater than composite electrodes bound with polyvinylidene fluoride (PVDF) and similar to CDI electrodes composed of chemically modified carbon. Polysaccharide binders did not modify the charge balance in the carbon micropores but did shift the discharge voltage of maximum adsorption, enabling a shift in operating voltage that prolonged cycle lifetime without a significant loss in performance. The mechanism of improved salt accumulation with polysaccharide binders was explored with a one-dimensional model that integrated CDI and ion-exchange membrane covered (MCDI) sub-units. Model simulations indicate that carbon macropores covered with thin layers of charged polysaccharides increase adsorption by a sequential accumulation and release of salt to depleted uncovered pores.

LanguageEnglish (US)
Pages388-397
Number of pages10
JournalWater Research
Volume148
DOIs
StatePublished - Jan 1 2019

Fingerprint

Polysaccharides
polysaccharide
Binders
electrode
Salts
salt
adsorption
Adsorption
Electrodes
macropore
Carbon
carbon
Ion exchange membranes
ion
Composite materials
Ions
Electric potential
Chitosan
fluoride
energy

Keywords

  • Capacitive deionization
  • Carboxymethyl cellulose
  • Chitosan
  • Desalination
  • Structural polysaccharide binders

ASJC Scopus subject areas

  • Ecological Modeling
  • Water Science and Technology
  • Waste Management and Disposal
  • Pollution

Cite this

Enhancing capacitive deionization performance with charged structural polysaccharide electrode binders. / Kim, Martin; Cerro, Martina del; Hand, Steven; Cusick, Roland.

In: Water Research, Vol. 148, 01.01.2019, p. 388-397.

Research output: Contribution to journalArticle

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