Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex

Tyler J. Pearson; Majed S. Fataftah; Danna E. Freedman

doi:10.1039/c6cc06369a

Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex

Tyler J. Pearson, Majed S. Fataftah, Danna E. Freedman

Research output: Contribution to journal › Article › peer-review

Abstract

A novel Mn²⁺⋯Bi³⁺ heterobimetallic complex, featuring the closest Mn⋯Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn²⁺ to a heavy main group element, namely, bismuth.

Original language	English (US)
Pages (from-to)	11394-11397
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	76
DOIs	https://doi.org/10.1039/c6cc06369a
State	Published - 2016
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c6cc06369a

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title = "Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex",

abstract = "A novel Mn2+⋯Bi3+ heterobimetallic complex, featuring the closest Mn⋯Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn2+ to a heavy main group element, namely, bismuth.",

author = "Pearson, {Tyler J.} and Fataftah, {Majed S.} and Freedman, {Danna E.}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc06369a",

language = "English (US)",

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journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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AU - Pearson, Tyler J.

AU - Fataftah, Majed S.

AU - Freedman, Danna E.

PY - 2016

Y1 - 2016

N2 - A novel Mn2+⋯Bi3+ heterobimetallic complex, featuring the closest Mn⋯Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn2+ to a heavy main group element, namely, bismuth.

AB - A novel Mn2+⋯Bi3+ heterobimetallic complex, featuring the closest Mn⋯Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn2+ to a heavy main group element, namely, bismuth.

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DO - 10.1039/c6cc06369a

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JO - Chemical Communications

JF - Chemical Communications

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Enhancement of magnetic anisotropy in a Mn-Bi heterobimetallic complex

Abstract

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