ENFORCED SEGREGATED STACKING IN METALLOMACROCYCLIC 'METALS. ' NEW INFORMATION ON PHTHALOCYANINE DONOR-ACCEPTOR INTERACTIONS.

Tamotsu Inabe, Carl R. Kannewurf, Joseph W. Lyding, Michael K. Moguel, Tobin J. Marks

Research output: Contribution to journalConference article

Abstract

The chemical, structural, optical and electrical conductivity characteristics of the cofacially joined metallophthalocyanine polymer left bracket Si(Pc)O right bracket //n are probed in response to incremental doping by organic (dichlorodicyanoquinone) and inorganic (NO** plus BF//4** minus , NO** plus PF//6** minus ) oxidants of greatly differing structural and electronic characteristics. The achievable degree of partial oxidation, the homogeneity of the doping process, and the macroscopic mechanism of charge transport appear to be remarkably similar.

Original languageEnglish (US)
Pages (from-to)355-367
Number of pages13
JournalMolecular crystals and liquid crystals
Volume93
Issue number1-4
StatePublished - Jan 1 1982
Externally publishedYes
EventProc of the Int Conf on the Chem of the Org Solid State, 6th, Pt A - Freiburg, West Ger
Duration: Oct 4 1982Oct 8 1982

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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