Enantioselective hydroborations catalyzed by rhodium(+1) complexes

Kevin Burgess; Wilfred Adrianus van der Donk; Michael J. Ohlmeyer

doi:10.1016/S0957-4166(00)86113-3

Enantioselective hydroborations catalyzed by rhodium(+1) complexes

Kevin Burgess, Wilfred Adrianus van der Donk, Michael J. Ohlmeyer

Research output: Contribution to journal › Article › peer-review

Abstract

Enantioselective hydroborations of alkenes 1 - 4 with catecholborane were performed via catalysis with complexes containing the chiral ligands DIOP, BINAP, CHIRAPHOS, DIPAMP, BDPP, 2-MeODIOP, and 3-McODIOP. Alkenes 1 - 3 were also hydroborated with catecholborane derivatives 5 - 8 in the presence of Rh(+l)/DIOP catalysts. Trends in the observed optical purities are discussed.

Original language	English (US)
Pages (from-to)	613-621
Number of pages	9
Journal	Tetrahedron: Asymmetry
Volume	2
Issue number	7
DOIs	https://doi.org/10.1016/S0957-4166(00)86113-3
State	Published - 1991
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/S0957-4166(00)86113-3

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title = "Enantioselective hydroborations catalyzed by rhodium(+1) complexes",

abstract = "Enantioselective hydroborations of alkenes 1 - 4 with catecholborane were performed via catalysis with complexes containing the chiral ligands DIOP, BINAP, CHIRAPHOS, DIPAMP, BDPP, 2-MeODIOP, and 3-McODIOP. Alkenes 1 - 3 were also hydroborated with catecholborane derivatives 5 - 8 in the presence of Rh(+l)/DIOP catalysts. Trends in the observed optical purities are discussed.",

author = "Kevin Burgess and {van der Donk}, {Wilfred Adrianus} and Ohlmeyer, {Michael J.}",

year = "1991",

doi = "10.1016/S0957-4166(00)86113-3",

language = "English (US)",

volume = "2",

pages = "613--621",

journal = "Tetrahedron: Asymmetry",

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T1 - Enantioselective hydroborations catalyzed by rhodium(+1) complexes

AU - Burgess, Kevin

AU - van der Donk, Wilfred Adrianus

AU - Ohlmeyer, Michael J.

PY - 1991

Y1 - 1991

N2 - Enantioselective hydroborations of alkenes 1 - 4 with catecholborane were performed via catalysis with complexes containing the chiral ligands DIOP, BINAP, CHIRAPHOS, DIPAMP, BDPP, 2-MeODIOP, and 3-McODIOP. Alkenes 1 - 3 were also hydroborated with catecholborane derivatives 5 - 8 in the presence of Rh(+l)/DIOP catalysts. Trends in the observed optical purities are discussed.

AB - Enantioselective hydroborations of alkenes 1 - 4 with catecholborane were performed via catalysis with complexes containing the chiral ligands DIOP, BINAP, CHIRAPHOS, DIPAMP, BDPP, 2-MeODIOP, and 3-McODIOP. Alkenes 1 - 3 were also hydroborated with catecholborane derivatives 5 - 8 in the presence of Rh(+l)/DIOP catalysts. Trends in the observed optical purities are discussed.

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JO - Tetrahedron: Asymmetry

JF - Tetrahedron: Asymmetry

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ER -

Enantioselective hydroborations catalyzed by rhodium(+1) complexes

Abstract

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