Enantioselective hydroborations catalyzed by rhodium(+1) complexes

Kevin Burgess, Wilfred Adrianus van der Donk, Michael J. Ohlmeyer

Research output: Contribution to journalArticlepeer-review

Abstract

Enantioselective hydroborations of alkenes 1 - 4 with catecholborane were performed via catalysis with complexes containing the chiral ligands DIOP, BINAP, CHIRAPHOS, DIPAMP, BDPP, 2-MeODIOP, and 3-McODIOP. Alkenes 1 - 3 were also hydroborated with catecholborane derivatives 5 - 8 in the presence of Rh(+l)/DIOP catalysts. Trends in the observed optical purities are discussed.

Original languageEnglish (US)
Pages (from-to)613-621
Number of pages9
JournalTetrahedron: Asymmetry
Volume2
Issue number7
DOIs
StatePublished - 1991
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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