A method is proposed permitting the determination of the hfi parameters of nuclei in the nearest surroundings of a paramagnetic center by analysis of ESE modulation spectra, and an estimate of the number of these nuclei by analysis of ESE modulation envelopes in preliminary processing by appropriate frequency filters. The method is illustrated by the study of CH2OD radicals in a glassy CH3OD matrix.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry