Electronic Structure of Metal Chalcogen Cubane Clusters: Photoelectron Spectroscopic, Electrochemical, and Theoretical Studies of [(η-C5H4Me)TiS]4, [(η-C5H4Me)VS]4, [(η-C5H5)CrO]4, [(η-C5H4Me)CrO]4, [(η-C5H4Me)CrS]4, [(η-C5H4Me)CrSe]4, [(η-C5H4-iPr)MoS]4, and [(η-C5H4-iPr)MoSe]4

Cathryn E. Davies, Jennifer C. Green, Nikolas Kaltsoyannis, Jingui Qin, Catherine M. Redfern, Thomas Rauchfuss, Mark G. Woolhouse, Michael A. MacDonald

Research output: Contribution to journalArticlepeer-review

Abstract

Full title: Electronic structure of metal chalcogen cubane clusters: Photoelectron spectroscopic, electrochemical, and theoretical studies of [(η-C5H4Me)TiS]4, [(η-C5H4Me)VS]4, [(η-C5H5)CrO]4, [(η-C5H4Me)CrO]4, [(η-C5H4Me)CrS]4, [(η-C5H4Me)CrSe]4, [(η-C5H4iPr)MoS]4, and [(η-C5H4iPr)MoSe]4. He I and He II spectra of [(η-C5H4iPr)MoS]4, [(η-C5H4iPr)MoSe]4, [(η-C5H4Me)CrS]4, [(η-C5H4Me)CrSe]4, [(η-C5H4Me)TiS]4, [(η-C5H4Me)VS]4, [(η-C5H5)CrO]4, and [(η-C5H4Me)CrO]4 are presented. The photoelectron spectrum of [(η-C5H4iPr)MoS]4 has been measured using synchrotron radiation over the photon energy range 21-80 eV. Relative partial photoionization cross section and photoelectron branching ratio data are presented for the first six valence bands (binding energy 5.0-10.5 eV). The cross sections of the d bands show a p → d giant resonance in the photon energy range 39-60 eV. Intensity variations are interpreted in terms of the atomic orbital contributions to the molecular orbitals from which ionization is occurring. Similarities are observed between the low binding energy (4.8-7.5 eV) regions of the spectra of the sulfur and selenium derivatives of the group 6 elements and are interpreted in terms of ionization from molecular orbitals, composed largely of metal d-orbitals, delocalized over the metal tetrahedron. The molecular ion state ordering 2T2 < 2E < 2A1 is observed, the 2T2 and 2E states showing Jahn-Teller splitting. The a1 and e orbitals are metal-metal bonding whereas the t2 orbitals are nonbonding. Subsequent bands are assigned to cyclopentadienyl π orbitals and to metal-chalcogen bonding orbitals. The spectrum of [(η-C5H4Me)VS]4 is consistent with an a12e4t22 ground-state configuration for the metal-based orbitals, ionization from these three orbitals being easily identified. The ground state of [(η-C5H4Me)TiS]4 cannot be unambiguously assigned from the PE spectrum. The d band region of the [(η-C5H5)CrO]4 and [(η-C5H4Me)CrO]4 spectra shows fewer features. In these cases the metal d electrons are localized on the Cr ions, and the diamagnetism shown at low temperatures is the result of weak antiferromagnetic coupling. Cyclic voltammetry studies on [(η-C5H4iPr)MoS]4, [(η-C5H4iPr)MoSe]4, [(η-C5H4Me)CrS]4, [(η-C5H4Me)CrSe]4, [(η-C5H4Me)VS]4, and [(η-C5H4Me)CrO]4 reveal two reversible oxidations for all of the compounds except [(η-C5H4Me)CrO]4, which can sustain only one reversible oxidation, consistent with a smaller degree of metal d electron delocalization. Ultraviolet and visible spectroscopy data are presented for [(η-C5H4iPr)MoS]4, [(η-C5H4iPr)MoS]4+, [(η-C5H4Me)CrS]4, and [(η-C5H4Me)CrS]4+, in which the presence of a band in the spectra of the cations which is not observed in the spectra of the neutral molecules is attributed to a 2A12T2 transition.

Original languageEnglish (US)
Pages (from-to)3779-3791
Number of pages13
JournalInorganic Chemistry
Volume31
Issue number18
DOIs
StatePublished - 1992

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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Dive into the research topics of 'Electronic Structure of Metal Chalcogen Cubane Clusters: Photoelectron Spectroscopic, Electrochemical, and Theoretical Studies of [(η-C<sub>5</sub>H<sub>4</sub>Me)TiS]<sub>4</sub>, [(η-C<sub>5</sub>H<sub>4</sub>Me)VS]<sub>4</sub>, [(η-C<sub>5</sub>H<sub>5</sub>)CrO]<sub>4</sub>, [(η-C<sub>5</sub>H<sub>4</sub>Me)CrO]<sub>4</sub>, [(η-C<sub>5</sub>H<sub>4</sub>Me)CrS]<sub>4</sub>, [(η-C<sub>5</sub>H<sub>4</sub>Me)CrSe]<sub>4</sub>, [(η-C<sub>5</sub>H<sub>4</sub>-<sup>i</sup>Pr)MoS]<sub>4</sub>, and [(η-C<sub>5</sub>H<sub>4</sub>-<sup>i</sup>Pr)MoSe]<sub>4</sub>'. Together they form a unique fingerprint.

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