Electronic properties at a metal-solution interface as viewed by solid-state NMR

Yu Ye Tong; Cynthia Rice; Eric Oldfield; Andrzej Wieckowski

doi:10.1021/bk-2001-0789.ch003

Electronic properties at a metal-solution interface as viewed by solid-state NMR

Yu Ye Tong, Cynthia Rice, Eric Oldfield, Andrzej Wieckowski

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report our recent experimental and theoretical progress in our electrochemical NMR (EC-NMR) investigations of metal/solution interfaces. By correlating EC-NMR with in-situ infrared spectroelectrochemistry of chemisorbed CO, we discuss in detail, at an electronic level, the CO-metal (Pt) bonding as well as the electrode potential Stark effect. The ability to carry out the detailed EC-NMR investigations and couple it with other in-situ spectroscopic techniques opens a new promising avenue of research in the discipline.

Original language	English (US)
Pages (from-to)	26-39
Number of pages	14
Journal	ACS Symposium Series
Volume	789
DOIs	https://doi.org/10.1021/bk-2001-0789.ch003
State	Published - 2001

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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10.1021/bk-2001-0789.ch003

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abstract = "We report our recent experimental and theoretical progress in our electrochemical NMR (EC-NMR) investigations of metal/solution interfaces. By correlating EC-NMR with in-situ infrared spectroelectrochemistry of chemisorbed CO, we discuss in detail, at an electronic level, the CO-metal (Pt) bonding as well as the electrode potential Stark effect. The ability to carry out the detailed EC-NMR investigations and couple it with other in-situ spectroscopic techniques opens a new promising avenue of research in the discipline.",

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AU - Rice, Cynthia

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AU - Wieckowski, Andrzej

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N2 - We report our recent experimental and theoretical progress in our electrochemical NMR (EC-NMR) investigations of metal/solution interfaces. By correlating EC-NMR with in-situ infrared spectroelectrochemistry of chemisorbed CO, we discuss in detail, at an electronic level, the CO-metal (Pt) bonding as well as the electrode potential Stark effect. The ability to carry out the detailed EC-NMR investigations and couple it with other in-situ spectroscopic techniques opens a new promising avenue of research in the discipline.

AB - We report our recent experimental and theoretical progress in our electrochemical NMR (EC-NMR) investigations of metal/solution interfaces. By correlating EC-NMR with in-situ infrared spectroelectrochemistry of chemisorbed CO, we discuss in detail, at an electronic level, the CO-metal (Pt) bonding as well as the electrode potential Stark effect. The ability to carry out the detailed EC-NMR investigations and couple it with other in-situ spectroscopic techniques opens a new promising avenue of research in the discipline.

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Electronic properties at a metal-solution interface as viewed by solid-state NMR

Abstract

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