Efficient route to hydroxymethylfurans from sugars via transfer hydrogenation

Todsapon Thananatthanachon, Thomas B. Rauchfuss

Research output: Contribution to journalArticlepeer-review

Abstract

Tandem catalysis, relying on formic acid as an acid catalyst and as a source of hydrogen, provides a promising route to highly pure furanylmethanols. The new approach exploits (i) the use of DMSO to mediate highly efficient routes to furfurals and (ii) the ability of transfer hydrogenation catalysts to effect the hydrogenation, with good tolerance for DMSO.

Original languageEnglish (US)
Pages (from-to)1139-1141
Number of pages3
JournalChemSusChem
Volume3
Issue number10
DOIs
StatePublished - Oct 2010

Keywords

  • Biomass
  • Bis(hydroxymethyl)furan
  • Formic acid
  • Hydroxymethylfufural
  • Transfer hydrogenation

ASJC Scopus subject areas

  • Energy(all)
  • Environmental Chemistry
  • Materials Science(all)
  • Chemical Engineering(all)

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