Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols

Scott E. Denmark, Weitao Pan

Research output: Contribution to journalArticlepeer-review


Highly substituted alkenylsilanols (1), readily prepared from commercially available simple starting materials, are efficiently coupled with aryl or alkenyl halides in the presence of tetrabutylammonium fluoride (TBAF) and a palladium(0) catalyst. Yields are generally high and the reactions are highly stereoselective and compatible with a wide range of functional groups.

Original languageEnglish (US)
Pages (from-to)98-104
Number of pages7
JournalJournal of Organometallic Chemistry
Issue number1-2
StatePublished - Jul 1 2002


  • Alkenylsilanols
  • Cross-coupling
  • Palladium catalysis

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry


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