TY - GEN
T1 - Effect of catalyst used in the Sol-Gel process on the microstructure and adsorption/desorption performance of silica aerogels
AU - Nawaz, Kashif
AU - Schmidt, Shelly J.
AU - Jacobi, Anthony M.
N1 - Funding Information:
Authors acknowledge support provided by the Air Conditioning and Refrigeration Center (ACRC), Material Research Labs (MRL), and Department of Food Science and Human Nutrition at University of Illinois at Urbana Champaign . The project is financially supported by the ACRC (an NSF-founded Industry-University Cooperative Research Center) and the ASHRAE Grant-in-aid program.
PY - 2013
Y1 - 2013
N2 - Silica aerogels are often deployed as solid desiccants in enthalpy wheels used for dehumidifying ventilation air in airconditioning systems. These materials have good adsorption and desorption characteristics, but microstructure affects their moisture diffusivity. As the performance of desiccant systems depends on diffusivity, it is important to select a preparation method providing the desired aerogel microstructure for enhanced dehumidification performance. A study is described in which the structure of silica aerogels prepared by the Sol-Gel process is analyzed. The same precipitator (TMOS-Tetra methyl orthosilicate) and solvent (Methanol) are used to prepare all samples. It is found that density and microstructure are highly dependent on the catalyst used in the Sol-Gel process. Dynamic vapor sorption experiments are conducted to determine diffusivity. Microscopic images are analyzed to discern the structure and to relate it to corresponding adsorption or desorption performance parameters.
AB - Silica aerogels are often deployed as solid desiccants in enthalpy wheels used for dehumidifying ventilation air in airconditioning systems. These materials have good adsorption and desorption characteristics, but microstructure affects their moisture diffusivity. As the performance of desiccant systems depends on diffusivity, it is important to select a preparation method providing the desired aerogel microstructure for enhanced dehumidification performance. A study is described in which the structure of silica aerogels prepared by the Sol-Gel process is analyzed. The same precipitator (TMOS-Tetra methyl orthosilicate) and solvent (Methanol) are used to prepare all samples. It is found that density and microstructure are highly dependent on the catalyst used in the Sol-Gel process. Dynamic vapor sorption experiments are conducted to determine diffusivity. Microscopic images are analyzed to discern the structure and to relate it to corresponding adsorption or desorption performance parameters.
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U2 - 10.1115/IMECE2013-66768
DO - 10.1115/IMECE2013-66768
M3 - Conference contribution
AN - SCOPUS:84903456561
SN - 9780791856406
T3 - ASME International Mechanical Engineering Congress and Exposition, Proceedings (IMECE)
BT - Emerging Technologies
PB - American Society of Mechanical Engineers (ASME)
T2 - ASME 2013 International Mechanical Engineering Congress and Exposition, IMECE 2013
Y2 - 15 November 2013 through 21 November 2013
ER -