Effect of ash on hydrothermal liquefaction of high-ash content algal biomass

Wan Ting Chen, Wanyi Qian, Yuanhui Zhang, Zachary Mazur, Chih Ting Kuo, Karalyn Scheppe, Lance Charles Schideman, Brajendra Kumar Sharma

Research output: Contribution to journalArticle

Abstract

Previous studies demonstrate that the high ash contents appeared to inhibit the formation of biocrude oil in the hydrothermal liquefaction (HTL) processes. In order to investigate the effect of ash contents on the HTL reaction, mixed-culture algal biomass from wastewater systems (AW) was separated into two fractions (AW-41.8 and AW-38.5) and converted into biocrude oil via HTL at 300 °C for a 60 min reaction time (the previously determined optimum condition). Compared to AW biomass before screen pretreatments, the ash contents of AW-41.8 and AW-38.5 were respectively decreased from 53.3 wt% to 41.8 wt% and 38.5 wt%. Moreover, the higher heating value (HHV) of resulting biocrude oil was increased from 27.5 MJ/kg to 32.3 MJ/kg, and the fraction of light oil (boiling point of 110–300°C) was increased from 31 wt% to 49 wt%. The above results indicate that algal biomass with certain amounts of ash contents can be converted into biocrude oil with reasonable quality and quantity. To explore the range of concentrations of ash where it may present a positive effect on the biocrude oil yield or quality, further HTL conversions with pure algal feedstock and representative ash contents were conducted. The HHV and boiling point distribution of the algal biocrude oil was hardly affected when the ash contents in the algal feedstock was below 40 wt%. This fact substantiates the feasibility of using high-ash algae from wastewater treatment systems for HTL feedstocks and diminishes the necessity of multi-step pretreatments and modifications of high-ash algal biomass for biofuel application.

Original languageEnglish (US)
Pages (from-to)297-306
Number of pages10
JournalAlgal Research
Volume25
DOIs
StatePublished - Jul 1 2017

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ash content
oils
liquefaction
biomass
feedstocks
boiling point
pretreatment
heat
mixed culture
wastewater treatment
biofuels
wastewater
Algae
algal oils

Keywords

  • Ash
  • Catalysis
  • Hydrothermal liquefaction
  • Mixed-culture algae
  • Wastewater

ASJC Scopus subject areas

  • Agronomy and Crop Science

Cite this

Effect of ash on hydrothermal liquefaction of high-ash content algal biomass. / Chen, Wan Ting; Qian, Wanyi; Zhang, Yuanhui; Mazur, Zachary; Kuo, Chih Ting; Scheppe, Karalyn; Schideman, Lance Charles; Sharma, Brajendra Kumar.

In: Algal Research, Vol. 25, 01.07.2017, p. 297-306.

Research output: Contribution to journalArticle

Chen WT, Qian W, Zhang Y, Mazur Z, Kuo CT, Scheppe K et al. Effect of ash on hydrothermal liquefaction of high-ash content algal biomass. Algal Research. 2017 Jul 1;25:297-306. Available from, DOI: 10.1016/j.algal.2017.05.010

Chen, Wan Ting; Qian, Wanyi; Zhang, Yuanhui; Mazur, Zachary; Kuo, Chih Ting; Scheppe, Karalyn; Schideman, Lance Charles; Sharma, Brajendra Kumar / Effect of ash on hydrothermal liquefaction of high-ash content algal biomass.

In: Algal Research, Vol. 25, 01.07.2017, p. 297-306.

Research output: Contribution to journalArticle

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AU - Kuo,Chih Ting

AU - Scheppe,Karalyn

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AU - Sharma,Brajendra Kumar

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AB - Previous studies demonstrate that the high ash contents appeared to inhibit the formation of biocrude oil in the hydrothermal liquefaction (HTL) processes. In order to investigate the effect of ash contents on the HTL reaction, mixed-culture algal biomass from wastewater systems (AW) was separated into two fractions (AW-41.8 and AW-38.5) and converted into biocrude oil via HTL at 300 °C for a 60 min reaction time (the previously determined optimum condition). Compared to AW biomass before screen pretreatments, the ash contents of AW-41.8 and AW-38.5 were respectively decreased from 53.3 wt% to 41.8 wt% and 38.5 wt%. Moreover, the higher heating value (HHV) of resulting biocrude oil was increased from 27.5 MJ/kg to 32.3 MJ/kg, and the fraction of light oil (boiling point of 110–300°C) was increased from 31 wt% to 49 wt%. The above results indicate that algal biomass with certain amounts of ash contents can be converted into biocrude oil with reasonable quality and quantity. To explore the range of concentrations of ash where it may present a positive effect on the biocrude oil yield or quality, further HTL conversions with pure algal feedstock and representative ash contents were conducted. The HHV and boiling point distribution of the algal biocrude oil was hardly affected when the ash contents in the algal feedstock was below 40 wt%. This fact substantiates the feasibility of using high-ash algae from wastewater treatment systems for HTL feedstocks and diminishes the necessity of multi-step pretreatments and modifications of high-ash algal biomass for biofuel application.

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